9,10-Cyclohexenophenanthrene

Base Information

• Chemical Name: 9,10-Cyclohexenophenanthrene
• CAS No.: 5981-10-2
• Molecular Formula: C18H16
• Molecular Weight: 232.325
• Mol file: 5981-10-2.mol

Synonyms:Tetrahydro-1,2,3,4-triphenylen;1,2,3,4-tetrahydro-triphenylene;9,10-cyclohexenophenanthrene;1,2,3,4-Tetrahydro-triphenylen;9,10-cyclohexanophenanthrene;Triphenylene, 1,2,3,4-tetrahydro-;

Chemical Property of 9,10-Cyclohexenophenanthrene

Chemical Property:

• PSA: 0.00000
• LogP: 4.87180

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 9,10-Cyclohexenophenanthrene

There total 6 articles about 9,10-Cyclohexenophenanthrene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 58.0%

2-(Cyclohex-1-enyl)-diphenylether (151508-85-9) → 1,2,3,4-tetrahydrotriphenylene (5981-10-2) + 2-(6-Phenyl-cyclohex-1-enyl)-phenol + 2-(2-Phenyl-cyclohex-1-enyl)-phenol

Guidance literature:

In acetone; for 0.5h; Irradiation; other o-vinyl diphenyl ethers, other solvents, times;

DOI:10.1016/S0040-4039(00)74085-8

Reference yield: 44.0%

2-(Cyclohex-1-enyl)-diphenylether (151508-85-9) → 1,2,3,4-tetrahydrotriphenylene (5981-10-2) + 2-(2-Phenyl-cyclohex-1-enyl)-phenol

Guidance literature:

In methanol; for 1.5h; Irradiation;

DOI:10.1016/S0040-4039(00)74085-8

Reference yield: 12.0%

triphenylene (217-59-4) → 1,2,3,4-tetrahydrotriphenylene (5981-10-2) + 1,2,3,4,5,6,7,8,9,10,11,12-dodecahydrotriphenylene (1610-39-5) + 1,2,3,4,5,6,7,8-octahydro-triphenylene (13090-93-2)

Guidance literature:

With hydrogen; platinum(IV) oxide; In ethyl acetate; for 48h; under 1810.02 Torr; Ambient temperature;

DOI:10.1021/jo01302a010

upstream raw materials:

1,2,3,4,5,6,7,8,9,10,11,12-dodecahydrotriphenylene

triphenylene

2-(Cyclohex-1-enyl)-diphenylether

Downstream raw materials:

triphenylene

Refernces

• 1、 Pan, Horng-Bin,Wai, Chien M.. "Facile sonochemical synthesis of carbon nanotube-supported bimetallic Pt-Rh nanoparticles for room temperature hydrogenation of arenes". scheme or table. p. 1649 - 1660. Retrieved 2011/10/08.
• 2、 Yalpani, Mohamed,Koester, Roland. "Reduction of Polycyclic Arenes by BH Boranes, III. Partial Hydrogenation: From Anthracene to Coronene". . p. 719 - 724. Retrieved 2007/10/02.