[2-(acetyloxy)-5-nitro-2,5-dihydrofuran-2-yl]methanediyl diacetate

Base Information

• Chemical Name: [2-(acetyloxy)-5-nitro-2,5-dihydrofuran-2-yl]methanediyl diacetate
• CAS No.: 75631-81-1
• Molecular Formula: C11H13NO9
• Molecular Weight: 303.226
• Mol file: 75631-81-1.mol

Synonyms:

Chemical Property of [2-(acetyloxy)-5-nitro-2,5-dihydrofuran-2-yl]methanediyl diacetate

Chemical Property:

• Vapor Pressure: 2.87E-07mmHg at 25°C
• Boiling Point: 420.2°Cat760mmHg
• Flash Point: 182.4°C
• Density: 1.41g/cm³

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of [2-(acetyloxy)-5-nitro-2,5-dihydrofuran-2-yl]methanediyl diacetate

There total 3 articles about [2-(acetyloxy)-5-nitro-2,5-dihydrofuran-2-yl]methanediyl diacetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

furfural (98-01-1) + acetic anhydride (108-24-7) → (E)-2-acetoxy-5-nitro-2,5-dihydrofurfural diacetate (75631-81-1) + (Z)-2-acetoxy-5-nitro-2,5-dihydrofurfural diacetate (75631-82-2)

Guidance literature:

With sulfuric acid; nitric acid; at -5 ℃; for 4h;

DOI:10.1021/jo00370a012

Reference yield:

(furan-2-yl)methylene diacetate (613-75-2) + acetic anhydride (108-24-7) → cis-2-acetoxy-5-nitro-2,5-dihydro-2-furfural diacetate (5904-70-1,75631-81-1,75631-82-2,76045-41-5) + trans-2-acetoxy-5-nitro-2,5-dihydro-2-furfural diacetate (5904-70-1,75631-81-1,75631-82-2,76045-41-5)

Guidance literature:

With nitric acid; sulfuric acid;

DOI:10.1016/0040-4020(80)80080-9

Reference yield:

(furan-2-yl)methylene diacetate (613-75-2) + acetic anhydride (108-24-7) → cis-2-acetoxy-5-nitro-2,5-dihydro-2-furfural diacetate (5904-70-1,75631-81-1,75631-82-2,76045-41-5) + trans-2-acetoxy-5-nitro-2,5-dihydro-2-furfural diacetate (5904-70-1,75631-81-1,75631-82-2,76045-41-5)

Guidance literature:

With nitric acid; sulfuric acid;

DOI:10.1016/0040-4020(80)80080-9

upstream raw materials:

(furan-2-yl)methylene diacetate

acetic anhydride

furfural

Downstream raw materials:

5-nitro-2-furfuraldehyde diacetate

Refernces

• 1、 Mishnev, A. F.,Bleidelis, J. J.,Venters, K. K.. "MOLECULAR AND CRYSTALLINE STRUCTURE OF FURFURAL DIACETATE NITRATION INTERMEDIATE". . p. 1817 - 1820. Retrieved 2007/10/02.