bis(tosylmethyl isocyanide)iron(II) protoporphyrin IX dimethyl ester

Base Information

• Chemical Name: bis(tosylmethyl isocyanide)iron(II) protoporphyrin IX dimethyl ester
• CAS No.: 122056-85-3
• Molecular Formula: C₅₄H₅₄FeN₆O₈S₂
• Molecular Weight: 1035.04
• Mol file: 122056-85-3.mol

Synonyms:bis(tosylmethyl isocyanide)iron(II) protoporphyrin IX dimethyl ester

Chemical Property of bis(tosylmethyl isocyanide)iron(II) protoporphyrin IX dimethyl ester

Chemical Property:

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Technology Process of bis(tosylmethyl isocyanide)iron(II) protoporphyrin IX dimethyl ester

There total 1 articles about bis(tosylmethyl isocyanide)iron(II) protoporphyrin IX dimethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.8%

iron(III) protoporphyrin IX dimethyl ester chloride (49859-41-8,15741-03-4) + [(p-methylphenyl)sulfonylmethyl]isonitrile (38622-91-2,36635-61-7) → bis(tosylmethyl isocyanide)iron(II) protoporphyrin IX dimethyl ester (122056-85-3)

Guidance literature:

With Na₂S₂O₄; In pyridine; dichloromethane; water; addn. of aq. Na2S2O4 to Fe-complex in pyridine, pouring of mixt. into ice water, extraction (CH2Cl2), washing of org. phase (water), drying over Na2SO4, filtn., evapn., dissoln. (CH2Cl2), addn. of tosylate; chromy. (CH2Cl2/MeOH), recrystn. (benzene/light petroleum ether 1:1); elem. anal.;

DOI:10.1246/bcsj.61.3539

upstream raw materials:

iron(III) protoporphyrin IX dimethyl ester chloride

[(p-methylphenyl)sulfonylmethyl]isonitrile

Refernces