ethyl 3,4-bis(dodecyloxy)benzoate

Base Information

• Chemical Name: ethyl 3,4-bis(dodecyloxy)benzoate
• CAS No.: 773135-90-3
• Molecular Formula: C₃₃H₅₈O₄
• Molecular Weight: 518.821
• Mol file: 773135-90-3.mol

Synonyms:ethyl 3,4-bis(dodecyloxy)benzoate

Chemical Property of ethyl 3,4-bis(dodecyloxy)benzoate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of ethyl 3,4-bis(dodecyloxy)benzoate

There total 2 articles about ethyl 3,4-bis(dodecyloxy)benzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

1-bromo dodecane (112-29-8) + Ethyl protocatechuate (3943-89-3) → ethyl 3,4-bis(dodecyloxy)benzoate (773135-90-3)

Guidance literature:

With potassium carbonate; In N,N-dimethyl-formamide;

DOI:10.1021/ja210991f

Reference yield: 84.0%

Ethyl protocatechuate (3943-89-3) + 1-dodecylbromide (143-15-7) → ethyl 3,4-bis(dodecyloxy)benzoate (773135-90-3)

Guidance literature:

With potassium carbonate; In N,N-dimethyl-formamide; at 80 ℃; for 24h; Inert atmosphere;

DOI:10.1039/c6tc01260d

Reference yield: 93.0%

ethyl 3,4-bis(dodecyloxy)benzoate (773135-90-3) → 3,4-bis(n-dodecan-1-yloxy)benzyl alcohol (137916-67-7)

Guidance literature:

With lithium aluminium tetrahydride; In tetrahydrofuran; at 0 - 5 ℃; for 0.166667h; Glovebox; Schlenk technique; Inert atmosphere;

DOI:10.1002/chem.201705794

upstream raw materials:

Ethyl protocatechuate

1-dodecylbromide

1-bromo dodecane

Downstream raw materials:

3,4-didodecyloxybenzoic acid

3,4-Bis-dodecyloxy-benzoic acid 4-hydroxy-phenyl ester

3,4-Bis-dodecyloxy-benzoic acid 4-benzyloxy-phenyl ester

3,4-bis(dodecanyloxy)benzoyl chloride

Refernces

• 1、 Pradhan, Balaram,Pathak, Suraj Kumar,Gupta, Ravindra Kumar,Gupta, Monika,Pal, Santanu Kumar,Achalkumar, Ammathnadu S.. "Star-shaped fluorescent liquid crystals derived from s-triazine and 1,3,4-oxadiazole moieties". supporting information. p. 6117 - 6130. Retrieved 2016/07/06.
• 2、 Mysliwiec, Damian,Donnio, Bertrand,Chmielewski, Piotr J.,Heinrich, Benoit,Stepien, Marcin. "Peripherally fused porphyrins via the Scholl reaction: Synthesis, self-assembly, and mesomorphism". supporting information; scheme or table. p. 4822 - 4833. Retrieved 2012/05/19.