1,1,2,2,3,3,4,4,4-Nonafluoro-butane-1-sulfonic acid (E)-1-(diethoxy-phosphoryl)-2-phenyl-vinyl ester

Base Information

• Chemical Name: 1,1,2,2,3,3,4,4,4-Nonafluoro-butane-1-sulfonic acid (E)-1-(diethoxy-phosphoryl)-2-phenyl-vinyl ester
• CAS No.: 243137-81-7
• Molecular Formula: C₁₆H₁₆F₉O₆PS
• Molecular Weight: 538.325
• Mol file: 243137-81-7.mol

Synonyms:1,1,2,2,3,3,4,4,4-Nonafluoro-butane-1-sulfonic acid (E)-1-(diethoxy-phosphoryl)-2-phenyl-vinyl ester

Chemical Property of 1,1,2,2,3,3,4,4,4-Nonafluoro-butane-1-sulfonic acid (E)-1-(diethoxy-phosphoryl)-2-phenyl-vinyl ester

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1,1,2,2,3,3,4,4,4-Nonafluoro-butane-1-sulfonic acid (E)-1-(diethoxy-phosphoryl)-2-phenyl-vinyl ester

There total 1 articles about 1,1,2,2,3,3,4,4,4-Nonafluoro-butane-1-sulfonic acid (E)-1-(diethoxy-phosphoryl)-2-phenyl-vinyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 41.0%

Nonafluorobutanesulfonyl fluoride (375-72-4) + diethyl phenylacetylphosphonate (13504-37-5) → 1,1,2,2,3,3,4,4,4-Nonafluoro-butane-1-sulfonic acid (E)-1-(diethoxy-phosphoryl)-2-phenyl-vinyl ester (243137-81-7)

Guidance literature:

With 1,8-diazabicyclo[5.4.0]undec-7-ene; In tetrahydrofuran; at -45 ℃; for 4h;

DOI:10.1016/S0040-4039(99)00971-5

Reference yield: 95.0%

phenylacetylene (536-74-3) + 1,1,2,2,3,3,4,4,4-Nonafluoro-butane-1-sulfonic acid (E)-1-(diethoxy-phosphoryl)-2-phenyl-vinyl ester (243137-81-7) → {3-Phenyl-1-[1-phenyl-meth-(Z)-ylidene]-prop-2-ynyl}-phosphonic acid diethyl ester

Guidance literature:

With copper(l) iodide; N-ethyl-N,N-diisopropylamine; tetrakis(triphenylphosphine) palladium⁽⁰⁾; In toluene; Heating;

DOI:10.1016/S0040-4039(99)00971-5

Reference yield: 73.0%

phosphonic acid diethyl ester (762-04-9) + 1,1,2,2,3,3,4,4,4-Nonafluoro-butane-1-sulfonic acid (E)-1-(diethoxy-phosphoryl)-2-phenyl-vinyl ester (243137-81-7) → [1-(diethoxyphosphoryl)-2-phenyl-vinyl]-phosphonic acid diethyl ester (95601-03-9)

Guidance literature:

With N-ethyl-N,N-diisopropylamine; tetrakis(triphenylphosphine) palladium⁽⁰⁾; In N,N-dimethyl-formamide; at 110 ℃; for 1h;

DOI:10.1055/s-2003-41002

upstream raw materials:

Nonafluorobutanesulfonyl fluoride

diethyl phenylacetylphosphonate

Downstream raw materials:

[1-(diethoxyphosphoryl)-2-phenyl-vinyl]-phosphonic acid diethyl ester

Refernces