(3-bromonaphthalen-2-yloxy)(tert-butyl)diphenylsilane

Base Information

• Chemical Name: (3-bromonaphthalen-2-yloxy)(tert-butyl)diphenylsilane
• CAS No.: 1178513-70-6
• Molecular Formula: C₂₆H₂₅BrOSi
• Molecular Weight: 461.473
• Mol file: 1178513-70-6.mol

Synonyms:(3-bromonaphthalen-2-yloxy)(tert-butyl)diphenylsilane

Chemical Property of (3-bromonaphthalen-2-yloxy)(tert-butyl)diphenylsilane

Chemical Property:

Purity/Quality:

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MSDS Files:

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Technology Process of (3-bromonaphthalen-2-yloxy)(tert-butyl)diphenylsilane

There total 1 articles about (3-bromonaphthalen-2-yloxy)(tert-butyl)diphenylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

3-bromo-2-naphthol (30478-88-7) + tert-butylchlorodiphenylsilane (58479-61-1) → (3-bromonaphthalen-2-yloxy)(tert-butyl)diphenylsilane (1178513-70-6)

Guidance literature:

With dmap; triethylamine; In dichloromethane; at 0 - 20 ℃; Inert atmosphere;

DOI:10.1021/ja904791y

Reference yield: 83.0%

(3-bromonaphthalen-2-yloxy)(tert-butyl)diphenylsilane (1178513-70-6) → 5-tert-butyl-5-phenyl-5H-benzo[c]naphtho[2,3-e][1,2]oxasiline (1178513-93-3)

Guidance literature:

With palladium diacetate; caesium carbonate; tricyclohexylphosphine tetrafluoroborate; Trimethylacetic acid; In para-xylene; at 140 ℃; for 5h; Inert atmosphere; Molecular sieve;

DOI:10.1021/ja904791y

upstream raw materials:

3-bromo-2-naphthol

tert-butylchlorodiphenylsilane

Downstream raw materials:

5-tert-butyl-5-phenyl-5H-benzo[c]naphtho[2,3-e][1,2]oxasiline

Refernces