1,2-Cyclohexanediamine dinitratoplatinum

Base Information

• Chemical Name: 1,2-Cyclohexanediamine dinitratoplatinum
• CAS No.: 66900-67-2
• Molecular Formula: C₆H₁₄N₄O₆Pt
• Molecular Weight: 433.28
• Mol file: 66900-67-2.mol

Synonyms:(dinitrato(1R,2S-cyclohexanediamine)platinum(II));(Pt(NO3)2(cis-dach));1,2-cyclohexanediamine dinitratoplatinum;1,2-cyclohexanediamine dinitratoplatinum, SP-4-2-(1R-trans)-isomer;1,2-cyclohexanediamine dinitratoplatinum, SP-4-2-(1S-trans)-isomer;1,2-cyclohexanediamine dinitratoplatinum, SP-4-3-(cis)-isomer;NSC 239851;NSC-239851;platinum(II) 1,2-diaminocyclohexane nitrate

Chemical Property of 1,2-Cyclohexanediamine dinitratoplatinum

Chemical Property:

• Vapor Pressure: 0.46mmHg at 25°C
• Boiling Point: 193.6°C at 760 mmHg
• Flash Point: 75°C
• PSA: 134.16000
• LogP: 1.42490
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 8
• Rotatable Bond Count: 0
• Exact Mass: 433.056129
• Heavy Atom Count: 17
• Complexity: 81.7

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1CCC(C(C1)N)N.[N+](=O)([O-])[O-].[N+](=O)([O-])[O-].[Pt+2]

Technology Process of 1,2-Cyclohexanediamine dinitratoplatinum

There total 2 articles about 1,2-Cyclohexanediamine dinitratoplatinum which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

{(1R,2R)-cyclohexane-1,2-diamine}dichloridoplatinum(II) (38780-40-4,52691-24-4,61848-70-2,61848-66-6,61848-62-2) → cis-dinitrato(1,2-diaminocyclohexane)platinum(II) (66900-68-3,66900-69-4,66900-67-2,60732-70-9,125515-54-0)

Guidance literature:

With silver nitrate; In water; solns. of the Pt-complex and AgNO3 in water were mixed, stirred (N2) in the absence of light at 25°C for 2 h; filtn. prepd. in aq. soln.;

DOI:10.1007/BF02546607

Reference yield:

{(1R,2R)-cyclohexane-1,2-diamine}dichloridoplatinum(II) (38780-40-4,52691-24-4,61848-70-2,61848-66-6,61848-62-2) + silver nitrate → cis-dinitrato(1,2-diaminocyclohexane)platinum(II) (66900-68-3,66900-69-4,66900-67-2,60732-70-9,125515-54-0)

Guidance literature:

In water; byproducts: AgCl; stirring for 2 h at room temp. in the absence of light and oxygen;; filtered; not isolated;;

DOI:10.1016/S0020-1693(00)81554-6

Reference yield:

N-phenylsalicylaldimine (779-84-0) + cis-dinitrato(1,2-diaminocyclohexane)platinum(II) (66900-68-3,66900-69-4,66900-67-2,60732-70-9,125515-54-0) → N-phenylsalicylaldimino(1,2-diaminocyclohexane)platinum(II) nitrate

Guidance literature:

In water; aq. soln. of dinitrato(1,2-diaminocyclohexane)platinum(II) + a solution of N-phenylsalicylaldimine in ethanol was stirred (N2) in the absence of light at 50°C for 24 h; filtn. washed with acetone, dried over drierite at reduced pressure;

DOI:10.1007/BF02546607

upstream raw materials:

{(1R,2R)-cyclohexane-1,2-diamine}dichloridoplatinum(II)

Refernces