N,N-diallyl-4-bromobenzenamine

Base Information

• Chemical Name: N,N-diallyl-4-bromobenzenamine
• CAS No.: 30438-95-0
• Molecular Formula: C₁₂H₁₄BrN
• Molecular Weight: 252.154
• Mol file: 30438-95-0.mol

Synonyms:N,N-diallyl-4-bromobenzenamine

Chemical Property of N,N-diallyl-4-bromobenzenamine

Chemical Property:

Purity/Quality:

Safty Information:

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• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of N,N-diallyl-4-bromobenzenamine

There total 10 articles about N,N-diallyl-4-bromobenzenamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

N,N-diallylaniline (6247-00-3) → N,N-diallyl-4-bromobenzenamine (30438-95-0)

Guidance literature:

With tetraethylammonium bromide; 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione; In acetonitrile; at 20 ℃; for 0.166667h; chemoselective reaction;

DOI:10.1080/00397910801914103

Reference yield: 95.0%

allyl bromide (106-95-6) + 4-bromo-aniline (106-40-1) → N,N-diallyl-4-bromobenzenamine (30438-95-0)

Guidance literature:

4-bromo-aniline; With cetyltrimethylammonim bromide; sodium carbonate; In N,N-dimethyl-formamide; for 0.0833333h;

allyl bromide; In N,N-dimethyl-formamide; at 130 ℃; for 0.333333h; Microwave irradiation;

DOI:10.1016/j.tetlet.2014.03.044

Reference yield: 82.0%

O-benzoyl-N,N-diallylhydroxylamine (874480-14-5) + (4-bromophenyl)[2-(hydroxymethyl)phenyl]dimethylsilane (947515-73-3) → N,N-diallyl-4-bromobenzenamine (30438-95-0)

Guidance literature:

With copper(l) iodide; johnphos; lithium tert-butoxide; In 1,4-dioxane; at 20 ℃; for 4h; Inert atmosphere; Schlenk technique;

DOI:10.1021/ol303222s

upstream raw materials:

allyl tosylate

4-bromo-aniline

allyl iodid

cetyltrimethylammonium bromide

Downstream raw materials:

4-(4-Diallylamino-phenyl)-4H-pyridine-1-carboxylic acid phenyl ester

1-(4-bromo-phenyl)-pyrrolidine

N,N-diallylaniline

N-(1-(4-aminophenyl)-3-methyl-1-oxobutan-2-yl)benzamide

Refernces

• 1、 Ellern, Arkady,Peterson, Joshua P.,Winter, Arthur H.. "Spin Delocalization, Polarization, and London Dispersion Forces Govern the Formation of Diradical Pimers". supporting information. p. 5304 - 5313. Retrieved 2020/04/08.
• 2、 Liu, Meiyu,Wang, Xie,Sun, Xiaoliang,He, Wei. "Highly selective N-allylation of anilines under microwave irradiation". . p. 2711 - 2714. Retrieved 2014/05/06.