1-dimethylalumina-2-methylhexane

Base Information

• Chemical Name: 1-dimethylalumina-2-methylhexane
• CAS No.: 1197215-55-6
• Molecular Formula: C₉H₂₁Al
• Molecular Weight: 156.247
• Mol file: 1197215-55-6.mol

Synonyms:1-dimethylalumina-2-methylhexane

Chemical Property of 1-dimethylalumina-2-methylhexane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1-dimethylalumina-2-methylhexane

There total 2 articles about 1-dimethylalumina-2-methylhexane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 53.0%

1-hexene (592-41-6,25067-06-5) + trimethylaluminum (75-24-1) → 2-methyl-1-hexene (6094-02-6) + C8H19Al (1197215-56-7) + 1-dimethylalumina-2-methylhexane (1197215-55-6)

Guidance literature:

1-hexene; trimethylaluminum; With C₂₀H₃₀Cl₂Zr^(2-); In dichloromethane; at 22 ℃; for 24h; Inert atmosphere;

With hydrogenchloride; In dichloromethane; water; at 0 ℃;

DOI:10.1016/j.jorganchem.2009.07.037

Reference yield:

1-hexene (592-41-6,25067-06-5) + trimethylaluminum (75-24-1) → 2-methyl-1-hexene (6094-02-6) + 2-pentyl-non-1-ene (53056-37-4) + C8H19Al (1197215-56-7) + 1-dimethylalumina-2-methylhexane (1197215-55-6)

Guidance literature:

With zirconocene methyl chloride; In dichloromethane; at 22 ℃; for 24h; Reagent/catalyst; Solvent; Inert atmosphere; Schlenk technique;

DOI:10.1039/c8dt04156c

upstream raw materials:

1-hexene

trimethylaluminum

Refernces

• 1、 Parfenova, Lyudmila V.,Kovyazin, Pavel V.,Gabdrakhmanov, Vener Z.,Istomina, Galina P.,Ivchenko, Pavel V.,Nifant'Ev, Ilya E.,Khalilov, Leonard M.,Dzhemilev, Usein M.. "Ligand exchange processes in zirconocene dichloride-trimethylaluminum bimetallic systems and their catalytic properties in reaction with alkenes". . p. 16918 - 16937. Retrieved 2018.