Technology Process of (Z)-1-(4-nitrophenyl)ethanone O-benzyloxime
There total 4 articles about (Z)-1-(4-nitrophenyl)ethanone O-benzyloxime which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
(Z)-1-(4-nitrophenyl)ethanone oxime;
With
sodium hydride;
In
N,N-dimethyl-formamide;
at 0 ℃;
for 1h;
benzyl bromide;
In
N,N-dimethyl-formamide;
at 20 ℃;
for 18h;
DOI:10.1021/jo400371x
- Guidance literature:
-
Multi-step reaction with 4 steps
1.1: bromine / dichloromethane / 1 h / 0 °C
2.1: hydroxylamine hydrochloride / water; methanol / 25 °C
3.1: sodium tetrahydroborate / water; acetonitrile / 0.17 h / 25 °C
4.1: sodium hydride / N,N-dimethyl-formamide / 1 h / 0 °C
4.2: 18 h / 20 °C
With
sodium tetrahydroborate; hydroxylamine hydrochloride; bromine; sodium hydride;
In
methanol; dichloromethane; water; N,N-dimethyl-formamide; acetonitrile;
DOI:10.1021/jo400371x
- Guidance literature:
-
Multi-step reaction with 3 steps
1.1: hydroxylamine hydrochloride / water; methanol / 25 °C
2.1: sodium tetrahydroborate / water; acetonitrile / 0.17 h / 25 °C
3.1: sodium hydride / N,N-dimethyl-formamide / 1 h / 0 °C
3.2: 18 h / 20 °C
With
sodium tetrahydroborate; hydroxylamine hydrochloride; sodium hydride;
In
methanol; water; N,N-dimethyl-formamide; acetonitrile;
DOI:10.1021/jo400371x
