gamma-Diasarone

Base Information

• Chemical Name: gamma-Diasarone
• CAS No.: 80434-33-9
• Molecular Formula: C₂₄H₃₂O₆
• Molecular Weight: 416.514
• Mol file: 80434-33-9.mol

Synonyms:

Chemical Property of gamma-Diasarone

Chemical Property:

• PSA: 55.38000
• LogP: 5.01340

Purity/Quality:

98%min ^*data from raw suppliers

gamma-Diasarone ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of gamma-Diasarone

There total 5 articles about gamma-Diasarone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

1-ethylidene-4,5,7-trimethoxy-2-methyl-3-(2,4,5-trimethoxyphenyl)-1H-indene → γ-diasarone (80434-33-9,101910-59-2,130746-43-9,137490-15-4)

Guidance literature:

With palladium 10% on activated carbon; hydrogen; In methanol; at 20 ℃; for 24h;

DOI:10.1021/acs.orglett.1c04243

Reference yield: 61.0%

α-asarone (2883-98-9) + 1-(2,4,5-Trimethoxyphenyl)propan-1-ol (29652-82-2) → γ-diasarone (80434-33-9,101910-59-2,130746-43-9,137490-15-4)

Guidance literature:

With tin(IV) chloride; In dichloromethane;

DOI:10.1016/j.tet.2008.02.034

Reference yield: 39.0%

α-asarone (2883-98-9) → γ-diasarone (80434-33-9,101910-59-2,130746-43-9,137490-15-4)

Guidance literature:

With silver trifluoromethanesulfonate; gold(I) chloride; at 20 ℃; for 3h; stereoselective reaction; Ionic liquid;

DOI:10.1055/s-0035-1561604

upstream raw materials:

α-asarone

ethanol

1-(2,4,5-Trimethoxyphenyl)propan-1-ol

Refernces

• 1、 Lanta?o, Beatriz,Aguirre, José M.,Drago, Eleonora V.,de la Faba, Diego J.,Pomilio, Nicolás,Mufato, Jorge D.. "Effect of methoxyl groups on the NMR spectra: configuration and conformation of natural and synthetic indanic and tetralinic structures". . p. 619 - 633. Retrieved 2017/06/08.
• 2、 Lanta?o, Beatriz,Aguirre, José Manuel,Ugliarolo, Esteban Ariel,Benegas, María Laura,Moltrasio, Graciela Yolanda. "Scope of the formal [3+2] cycloaddition for the synthesis of substituted 3-arylindanes and related compounds". . p. 4090 - 4102. Retrieved 2008/09/20.