1,1,1-Trimethylhydrazinium iodide

Base Information

• Chemical Name: 1,1,1-Trimethylhydrazinium iodide
• CAS No.: 3288-80-0
• Molecular Formula: C3H11N2.I
• Molecular Weight: 202.038
• Hs Code.: 2928009090
• European Community (EC) Number: 628-240-7
• NSC Number: 123999,33596
• DSSTox Substance ID: DTXSID00954539
• Mol file: 3288-80-0.mol

Synonyms:1,1,1-Trimethylhydrazinium iodide;3288-80-0;Trimethylhydrazonium iodide;HYDRAZINIUM, 1,1,1-TRIMETHYL-, IODIDE;amino(trimethyl)azanium;iodide;1,1,1-TRIMETHYLHYDRAZINIUMIODIDE;trimethylhydrazinium iodide;NSC 33596;NSC 123999;Hydrazonium, 1,1,1-trimethyl-, iodide;1,1-Trimethylhydrazinium iodide;Hydrazinium, 1,1,1-trimethyl-, iodide (1:1);Hydrazinium,1,1-trimethyl-, iodide;Hydrazonium,1,1-trimethyl-, iodide;SCHEMBL1116248;C3H11N2.I;DTXSID00954539;C3-H11-N2.I;NSC33596;MFCD00464984;NSC-33596;NSC123999;AKOS015904453;1,1,1-Trimethylhydrazin-1-ium iodide;NSC-123999;SS-4858;1,1,1-Trimethylhydrazinium iodide 97%;LS-77027;CS-0530352;FT-0745116;F87342;J-018916

Chemical Property of 1,1,1-Trimethylhydrazinium iodide

Chemical Property:

• Melting Point: 225-230 °C (dec.)(lit.)
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 0
• Exact Mass: 201.99670
• Heavy Atom Count: 6
• Complexity: 26.4

Purity/Quality:

98%,99%, ^*data from raw suppliers

1,1,1-Trimethylhydrazinium iodide ^*data from reagent suppliers

Safty Information:

• Pictogram(s): T
• Hazard Codes: T
• Statements: 61-36/37/38
• Safety Statements: 53-36/37/39-45

MSDS Files:

SDS file from LookChem

Useful:

• Chemical Classes: Nitrogen Compounds -> Hydrazines
• Canonical SMILES: C[N+](C)(C)N.[I-]
• Uses: 1,1,1-Trimethylhydrazinium iodide (TMHI) may be employed for the amination of 1-X-3,5-dinitrobenzenes.

Technology Process of 1,1,1-Trimethylhydrazinium iodide

There total 8 articles about 1,1,1-Trimethylhydrazinium iodide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

N,N-Dimethylhydrazine (57-14-7) + methyl iodide (74-88-4) → N,N,N-trimethylhydrazinium iodide (3288-80-0)

Guidance literature:

In tetrahydrofuran; at 25 ℃; Cooling with ice;

DOI:10.1002/chem.200902725

Reference yield: 46.0%

2-[3-[(2-hydroxyethyl)sulfanyl]butylidene]-1,1,1-trimethylhydrazinium iodide → N,N,N-trimethylhydrazinium iodide (3288-80-0)

Guidance literature:

With methyl iodide; In methanol; for 72h;

DOI:10.1007/s11176-005-0341-8

Reference yield:

trimethylamine (75-50-3) → N,N,N-trimethylhydrazinium iodide (3288-80-0)

Guidance literature:

With chloroamine;

DOI:10.1021/ja01587a033

upstream raw materials:

N,N-Dimethylhydrazine

methyl iodide

trimethylamine

Downstream raw materials:

[5-(3-amino-5-chloro-4-nitrophenyl)-10,15,20-tris(3-chlorophenyl)-21H,23H-porphinato(2-)-κN21,κN22,κN23,κN24]copper

[5-(3-amino-4-nitrophenyl)-10-(4-nitrophenyl)-15,20-diphenyl-21H,23H-porphinato(2-)-κN21,κN22,κN23,κN24]copper

[5,10-bis(3-amino-4-nitrophenyl)-15,20-diphenyl-21H,23H-porphinato(2-)-κN21,κN22,κN23,κN24]copper

[5-(3-amino-4-nitrophenyl)-10-(4-nitrophenyl)-15,20-diphenyl-21H,23H-porphinato(2-)-κN21,κN22,κN23,κN24]zinc

Refernces

• 1、 Schulze,Scott,Chavez. "A high density pyrazolo-triazine explosive (PTX)". supporting information. p. 17963 - 17965. Retrieved 2015/09/02.
• 2、 Ostrowski, Stanislaw,Grzyb, Sebastian,Mikus, Agnieszka. "Direct amination of meso-tetraarylporphyrin derivatives - Easy route to A3B-, A2BC-, and A2B2-type porphyrins bearing two nitrogen-containing substituents at the meso-positioned phenyl groups". . p. 2000 - 2008. Retrieved 2008/03/13.