Cyclododecene, (E)-

Base Information

• Chemical Name: Cyclododecene, (E)-
• CAS No.: 1486-75-5
• Molecular Formula: C12H22
• Molecular Weight: 166.307
• Hs Code.: 2902199090
• European Community (EC) Number: 216-117-7
• DSSTox Substance ID: DTXSID20880669
• Wikidata: Q24706333
• Mol file: 1486-75-5.mol

Synonyms:1501-82-2;Cyclododecene, (E)-;Cyciododecene;DTXSID20880669;FT-0624165;D89251

Chemical Property of Cyclododecene, (E)-

Chemical Property:

• Vapor Pressure: 0.0665mmHg at 25°C
• Refractive Index: 1.4850
• Boiling Point: 238.1°Cat760mmHg
• Flash Point: 93.9°C
• PSA: 0.00000
• Density: 0.806g/cm³
• LogP: 4.45720
• XLogP3: 5.7
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 166.172150702
• Heavy Atom Count: 12
• Complexity: 99.2

Purity/Quality:

98%Min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Chemical Classes: Other Classes -> Aliphatics, Unsaturated
• Canonical SMILES: C1CCCCCC=CCCCC1

Technology Process of Cyclododecene, (E)-

There total 24 articles about Cyclododecene, (E)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 66.0%

threo-2-bromocyclododecanol (61153-78-4,61247-14-1,83602-77-1) → cis-cyclododecene (1129-89-1) + (E)-Cyclododecen (1486-75-5) + cyclododecanol (1724-39-6) + cyclododecanone (830-13-7)

Guidance literature:

With chlorotris(triphenylphosphine)cobalt(I); triethylamine; for 6h; Yield given; Ambient temperature;

DOI:10.1016/S0040-4039(00)87973-3

Reference yield: 40.0%

threo-2-bromocyclododecanol (61153-78-4,61247-14-1,83602-77-1) → (E)-Cyclododecen (1486-75-5) + cyclododecanol (1724-39-6) + cyclododecanone (830-13-7)

Guidance literature:

With chlorotris(triphenylphosphine)cobalt(I); triethylamine; In benzene; for 3h; Ambient temperature;

Reference yield: 40.0%

erythro-2-bromocyclododecanol (61153-78-4,61247-14-1,83602-77-1) → cis-cyclododecene (1129-89-1) + (E)-Cyclododecen (1486-75-5) + cyclododecanol (1724-39-6) + cyclododecanone (830-13-7)

Guidance literature:

With chlorotris(triphenylphosphine)cobalt(I); for 6h; Ambient temperature;

DOI:10.1016/S0040-4039(00)87973-3

upstream raw materials:

(1E,5E,9Z)-cyclododeca-1,5,9-triene

Cyclododecyl phenyl selenide

cyclododecanol

1-(ethylsulfinyl)cyclododecene

Downstream raw materials:

cyclododecanone

dodecanedial

cyclododecene

2-fluorocyclododec-2-enol

Refernces

• 1、 -. "METHOD FOR PRODUCING CYCLODODECANONE". Page/Page column 27-28. . Retrieved 2008/06/13.
• 2、 Barton, Derek H. R.,Parekh, Shyamal I.,Tajbakhsh, Mahmoud,Theodorakis, Emmanouil A.,Tse, Chi-Lam. "A Convenient and High Yielding Procedure for the Preparation of Isoselenocyanates. Synthesis and Reactivity of O-Alkylselenocarbamates.". . p. 639 - 654. Retrieved 2007/10/02.