Benzyl trichloromethyl sulfone

Base Information

• Chemical Name: Benzyl trichloromethyl sulfone
• CAS No.: 15894-11-8
• Molecular Formula: C₈H₇Cl₃O₂S
• Molecular Weight: 273.567
• Mol file: 15894-11-8.mol

Synonyms:Benzyl trichloromethyl sulfone

Chemical Property of Benzyl trichloromethyl sulfone

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of Benzyl trichloromethyl sulfone

There total 3 articles about Benzyl trichloromethyl sulfone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

Benzyl trichloromethanesulfinate (55613-64-4) → Benzyl trichloromethyl sulfone (15894-11-8)

Guidance literature:

With 2,6-dimethylpyridine; In acetonitrile; at 100 ℃; for 4.5h;

DOI:10.1016/S0040-4020(01)88389-7

Reference yield:

Benzyl trichloromethanesulfenate (13029-10-2) → Benzyl trichloromethyl sulfone (15894-11-8)

Guidance literature:

Multi-step reaction with 2 steps

1: 98 percent / 80percent MCPBA / CH₂Cl₂ / 1.) 0 deg C, 2.) 1 h, room temperature

2: 75 percent / 2,6-lutidine / acetonitrile / 4.5 h / 100 °C

With 2,6-dimethylpyridine; 3-chloro-benzenecarboperoxoic acid; In dichloromethane; acetonitrile;

DOI:10.1016/S0040-4020(01)88389-7

Reference yield:

benzyl chloromethyl sulfide (3970-13-6) → Benzyl trichloromethyl sulfone (15894-11-8)

Guidance literature:

Multistep reaction; (i) SO₂Cl₂, pentane, (ii) SO₂Cl₂, PE, (iii) MCPBA, CHCl₃;

DOI:10.1021/ja01026a040

upstream raw materials:

benzyl chloromethyl sulfide

Benzyl trichloromethanesulfinate

Benzyl trichloromethanesulfenate

Downstream raw materials:

benzoylmethanesulfonic acid

Refernces