Dodecyl methyl sulfoxide

Base Information

• Chemical Name: Dodecyl methyl sulfoxide
• CAS No.: 3079-30-9
• Molecular Formula: C13H28 O S
• Molecular Weight: 232.431
• Hs Code.: 2930909090
• European Community (EC) Number: 221-369-6
• DSSTox Substance ID: DTXSID00952994
• Nikkaji Number: J104.360I
• ChEMBL ID: CHEMBL1782215
• Mol file: 3079-30-9.mol

Synonyms:Dodecyl methyl sulfoxide;3079-30-9;1-(Methylsulfinyl)dodecane;1-methylsulfinyldodecane;1-methanesulfinyldodecane;Dodecane, 1-(methylsulfinyl)-;Sulfoxide, dodecyl methyl;1-(Methylsulphinyl)dodecane;C13H28OS;EINECS 221-369-6;Methyl lauryl sulfoxide;methyl dodecyl sulfoxide;n-Dodecyl methyl sulfoxide;1-(Methanesulfinyl)dodecane;1-(Methylsulfinyl)dodecane #;SCHEMBL313076;Dodecyl methyl sulfoxide, 98%;CHEMBL1782215;DTXSID00952994;MFCD02326311;AKOS015912582;CS-W010351;AMY202100068;AS-59711;D70250;A876095;J-650018;J-650229

Chemical Property of Dodecyl methyl sulfoxide

Chemical Property:

• Vapor Pressure: 6.13E-05mmHg at 25°C
• Melting Point: 59-63 °C(lit.)
• Boiling Point: 356.1°Cat760mmHg
• Flash Point: 169.2°C
• PSA: 36.28000
• Density: 0.92g/cm³
• LogP: 5.15150
• Storage Temp.: Sealed in dry,Room Temperature
• XLogP3: 4.9
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 11
• Exact Mass: 232.18608669
• Heavy Atom Count: 15
• Complexity: 146

Purity/Quality:

98%,99%, ^*data from raw suppliers

Dodecyl methyl sulfoxide ^*data from reagent suppliers

Safty Information:

• Safety Statements: 22-24/25

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCCCCCCCCCCS(=O)C
• Uses: Dodecyl methyl sulfoxide can be used as a substitute for dimethyl sulfoxide in Swern oxidation of primary allylic and benzylic alcohols to the corresponding aldehydes and secondary alcohols to the corresponding ketones.

Technology Process of Dodecyl methyl sulfoxide

There total 6 articles about Dodecyl methyl sulfoxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

dodecyl methyl sulfide (3698-89-3) → methyl dodecyl sulfoxide (3079-30-9)

Guidance literature:

With dihydrogen peroxide; In neat (no solvent); at 20 ℃; for 0.333333h;

DOI:10.1002/aoc.5260

Reference yield:

dodecyl methyl sulfide (3698-89-3) → methyl dodecyl sulfoxide (3079-30-9) + S-dodecyl-S-methyl-sulfoximide (2749-36-2) + S-dodecyl-S-methyl-sulfodiimide (17616-89-6)

Guidance literature:

With chloroamine; ammonia; In isopropyl alcohol;

DOI:10.1021/ja00986a034

Reference yield:

dodecyl methyl sulfide (3698-89-3) → methyl dodecyl sulfoxide (3079-30-9) + 1-methylsulfonyldodecane (7560-61-4)

Guidance literature:

With dihydrogen peroxide; Mg-Al-LDH-WO₄; at 20 ℃; for 1.5h;

DOI:10.1039/b205292j

upstream raw materials:

dodecyl methyl sulfide

1-dodecylthiol

1-dodecylbromide

Downstream raw materials:

dodecyl methyl sulfide

N-benzylidene benzylamine

Refernces

• 1、 Hajjami, Maryam,Sheikhaei, Shiva,Gholamian, Fatemeh,Yousofvand, Zakieh. "Synthesis and Characterization of Magnetic Functionalized Ni and Cu Nano Catalysts and Their Application in Oxidation, Oxidative Coupling and Various Multi-Component Reactions". . p. 2420 - 2435. Retrieved 2021/01/04.
• 2、 Ashraf, Muhammad Aqeel,Liu, Zhenling,Peng, Wan-Xi. "Trisaminomethane–cobalt complex supported on Fe3O4 magnetic nanoparticles as an efficient recoverable nanocatalyst for oxidation of sulfides and C–S coupling reactions". . . Retrieved 2019/11/16.