bis[2,3-bis(hydroxyimino)-N-phenylbutyramidato-N2,N3]nickel

Base Information

• Chemical Name: bis[2,3-bis(hydroxyimino)-N-phenylbutyramidato-N2,N3]nickel
• CAS No.: 29204-84-0
• Molecular Formula: C₂₀H₂₀N₆NiO₆
• Molecular Weight: 499.105
• Mol file: 29204-84-0.mol

Synonyms:Nickel,bis(2,3-dioxobutyranilide 2,3-dioximato)- (8CI); Nickel,bis[2,3-bis(hydroxyimino)-N-phenylbutanamidato-N2,N3]-; Butanamide,2,3-bis(hydroxyimino)-N-phenyl-, nickel complex; C.I. 48545; C.I. PigmentYellow 153; Monolite Yellow 4RE-HD; PY 153; Paliotol Yellow 1770; PaliotolYellow L 1770; Paliotol Yellow L 1772; Pigment Yellow 153

Chemical Property of bis[2,3-bis(hydroxyimino)-N-phenylbutyramidato-N2,N3]nickel

Chemical Property:

• Melting Point: 212 °C
• PSA: 205.22000
• LogP: 0.84020

Purity/Quality:

99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of bis[2,3-bis(hydroxyimino)-N-phenylbutyramidato-N2,N3]nickel

There total 2 articles about bis[2,3-bis(hydroxyimino)-N-phenylbutyramidato-N2,N3]nickel which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.6%

nickel(II) chloride hexahydrate + N-phenyl-2,3-dihydroxyiminobutanamide (20333-11-3) → amphi-nickel(II)(N-phenyl-2,3-dihydroxyiminobutanamide)2 complex (91602-80-1,167638-07-5,29204-84-0)

Guidance literature:

With sodium hydroxide; In ethanol; mixing, NaOH addn. to set pH=5.4 (pptn.), stirring and boiling for 1 h, cooling (pptn.); washing (water, cold EtOH), drying; elem. anal.;

Reference yield: 27.0%

nickel(II) chloride hexahydrate + N-phenyl-2,3-dihydroxyiminobutanamide (20333-11-3) → anti-nickel(II)(N-phenyl-2,3-dihydroxyiminobutanamide)2 complex (167638-07-5,91602-80-1,29204-84-0)

Guidance literature:

With hydrogenchloride; sodium acetate; In ethanol; water; ligand diln. in 37% HCl, NaAc (aq.) addn. to set pH=1.5, addn. of NiCl (EtOH soln.), NaAc addn. to set pH=3, heating under reflux for 1 h, etheraddn., cooling (pptn.); washing (water-EtOH), vac. drying; elem. anal.;

upstream raw materials:

N-phenyl-2,3-dihydroxyiminobutanamide

Refernces