Titanium(IV) propoxide

Base Information

• Chemical Name: Titanium(IV) propoxide
• CAS No.: 3087-37-4
• Molecular Formula: C12H28O4Ti
• Molecular Weight: 284.232
• Hs Code.: 29051900
• European Community (EC) Number: 221-411-3
• UN Number: 2413
• Mol file: 3087-37-4.mol

Synonyms:Titanium(IV) propoxide;titanium n-propoxide;3087-37-4;?Titanium propoxide;Ti(OPr)4;SCHEMBL37081;Titanium(IV) propoxide, 98%;MFCD00009365;T3973

Chemical Property of Titanium(IV) propoxide

Chemical Property:

• Appearance/Colour: clear yellow liquid
• Vapor Pressure: 26.3mmHg at 25°C
• Melting Point: 20°C
• Refractive Index: n20/D 1.499(lit.)
• Boiling Point: 95.8 °C at 760 mmHg
• Flash Point: 15 °C
• PSA: 36.92000
• Density: 1.033 g/mL at 25 °C(lit.)
• LogP: 3.50920
• Storage Temp.: Store below +30°C.
• Sensitive.: Moisture Sensitive
• Water Solubility.: 1000g/L at 25℃
• Hydrogen Bond Donor Count: 4
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 4
• Exact Mass: 288.1780002
• Heavy Atom Count: 17
• Complexity: 50.5
• Transport DOT Label: Flammable Liquid

Purity/Quality:

99% ^*data from raw suppliers

Tetrapropyl orthotitanate for synthesis. CAS 3087-37-4, EC 221-411-3, chemical formula (CH CH CH O) Ti., for synthesis ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 10-36/37/38
• Safety Statements: 26-36/37/39

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: CCCO.CCCO.CCCO.CCCO.[Ti]

Technology Process of Titanium(IV) propoxide

There total 4 articles about Titanium(IV) propoxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

propan-1-ol (71-23-8) + titanium tetrachloride (7550-45-0) → titanium(IV) propoxide (3087-37-4)

Guidance literature:

With NH₄NO₃-NH₃; In tetrachloromethane; soln. of TiCl4 added to alcohol with cooling and stirring, soln. added to NH4NO3-NH3 with stirring and cooling at 0-15°C; organic layer separated, solvent removed, product distilled under vacuum;

Reference yield:

→ propan-1-ol; titanium-tripropylate (3087-37-4,22922-82-3,40849-91-0)

Guidance literature:

Herstellung;

Reference yield:

propan-1-ol (71-23-8) + titanium tetrachloride (7550-45-0) → titanium tetra-n-propoxide (3087-37-4)

Guidance literature:

With ammonia; In benzene; under N2; TiCl4 added slowly dropwise with stirring to alc. at 0°C; the resultant mixt. dild. with benzene; dry ammonia passed for 1 h; mixt. heated for 2-3 h on a water bath at 60-65°C; ppt. filtered off; distd. under vac.;

upstream raw materials:

propan-1-ol

titanium tetrachloride

Downstream raw materials:

(2SR,3SR)-methyl 2,3-diphenyloxirane-2-carboxylate

oxo(phthalocyaninato)titanium(IV)

n-propyl N-phenylcarbamate

Dipropyl carbonate

Refernces

• 1、 Yatluk,Suvorov. "SYNTHESIS OF ALKYL ORTHOTITANATES IN TWO-PHASE SYSTEMS.". . p. 1678 - 1680. Retrieved 2008/10/08.