cyclohexyl isoselenocyanate

Base Information

• Chemical Name: cyclohexyl isoselenocyanate
• CAS No.: 4426-69-1
• Molecular Formula: C₇H₁₁NSe
• Molecular Weight: 188.131
• Mol file: 4426-69-1.mol

Synonyms:cyclohexyl isoselenocyanate

Chemical Property of cyclohexyl isoselenocyanate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of cyclohexyl isoselenocyanate

There total 6 articles about cyclohexyl isoselenocyanate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

Cyclohexyl isocyanide (931-53-3) → cyclohexyl isoselenocyanate (4426-69-1)

Guidance literature:

With selenium; 1,8-diazabicyclo[5.4.0]undec-7-ene; In tetrahydrofuran; at 20 ℃; for 3h;

DOI:10.1021/jo0496704

Reference yield: 93.0%

Cyclohexyl isocyanate (3173-53-3) → cyclohexyl isoselenocyanate (4426-69-1)

Guidance literature:

With trimethylaluminum; 1,1,1,3,3,3-hexabutyldistannaselenane; In 1,4-dioxane; hexane; toluene; at 100 ℃; for 2h; Inert atmosphere;

DOI:10.1016/j.tetlet.2010.11.069

Reference yield:

4-cyclohexylselenosemicarbazide (92221-45-9) → diphenylselenide (1132-39-4) + cyclohexyl isoselenocyanate (4426-69-1)

Guidance literature:

With benzenediazonium tetrafluoroborate; In methanol; at 0 ℃; for 0.5h; Title compound not separated from byproducts;

upstream raw materials:

Cyclohexyl isocyanide

carbon diselenide

cyclohexylamine

4-cyclohexylselenosemicarbazide

Downstream raw materials:

N-cyclohexylselenocarbamate of octadecanol

isothiocyanatocyclohexane

N-cyclohexylselenocarbamate of cholestanol

Refernces

• 1、 Díaz, Marta,de Lucio, Héctor,Moreno, Esther,Espuelas, Socorro,Aydillo, Carlos,Jiménez-Ruiz, Antonio,Toro, Miguel ángel,Gutiérrez, Killian Jesús,Martínez-Merino, Victor,Cornejo, Alfonso,Palop, Juan Antonio,Sanmartín, Carmen,Planoa, Daniel. "Synthesis and leishmanicidal activity of novel urea, thiourea, and selenourea derivatives of diselenides". . . Retrieved 2019/05/21.
• 2、 Karabanovich, Galina,Roh, Jaroslav,Padělková, Zdeňka,Novák, Zdeněk,Vávrová, Kate?ina,Hrabálek, Alexandr. "One-pot synthesis of 1-substituted-5-alkylselanyl-1H-tetrazoles from isoselenocyanates: Unexpected formation of N-alkyl-N-arylcyanamides and (Z)-Se-alkyl-N-cyano-N,N′-diarylisoselenoureas". . p. 8798 - 8808. Retrieved 2013/09/23.