Trehalulose

Base Information

• Chemical Name: Trehalulose
• CAS No.: 51411-23-5
• Molecular Formula: C12H22O11
• Molecular Weight: 342.3
• European Community (EC) Number: 257-183-7
• UNII: H39U51DD7Q
• DSSTox Substance ID: DTXSID60965727
• Nikkaji Number: J261.707B
• Wikipedia: Trehalulose
• Wikidata: Q3541289
• Mol file: 51411-23-5.mol

Synonyms:trehalulose

Chemical Property of Trehalulose

Chemical Property:

• Boiling Point: 780.1 °C at 760 mmHg
• PKA: 11.85±0.20(Predicted)
• Flash Point: 290.8 °C
• PSA: 197.37000
• Density: 1.69 g/cm³
• LogP: -5.55300
• Storage Temp.: Hygroscopic, Refrigerator, Under inert atmosphere
• Solubility.: Methanol (Slightly, Sonicated), Water (Slightly)
• XLogP3: -4.8
• Hydrogen Bond Donor Count: 8
• Hydrogen Bond Acceptor Count: 11
• Rotatable Bond Count: 8
• Exact Mass: 342.11621151
• Heavy Atom Count: 23
• Complexity: 378

Purity/Quality:

99% ^*data from raw suppliers

Trehalulose ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C(C1C(C(C(C(O1)OCC(=O)C(C(C(CO)O)O)O)O)O)O)O
• Isomeric SMILES: C([C@@H]1[C@H]([C@@H]([C@H]([C@H](O1)OCC(=O)[C@H]([C@@H]([C@@H](CO)O)O)O)O)O)O)O
• Uses: Trehalulose is a biologically active disaccharide with health benefits.

Technology Process of Trehalulose

There total 6 articles about Trehalulose which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

Sucrose (57-50-1) → D-Fructose (57-48-7,18875-34-8) + D-glucose (50-99-7) + 1-O-α-D-glucopyranosyl-β-D-fructose (51411-23-5)

Guidance literature:

With trehalose synthase from Thermomonospora curvata DSM 43183; In aq. phosphate buffer; at 30 ℃; for 0.5h; pH=6.5; Kinetics; Enzymatic reaction;

DOI:10.1016/j.molcatb.2013.01.014

Reference yield:

Sucrose (57-50-1) → 1-O-α-D-glucopyranosyl-β-D-fructose (51411-23-5) + isomaltulose (13718-94-0)

Guidance literature:

With sucrose isomerase; In aq. phosphate buffer; at 30 ℃; for 0.333333h; pH=6; pH-value; Temperature; Kinetics; Enzymatic reaction;

DOI:10.1016/j.foodchem.2015.04.072

Reference yield:

D-2-deoxyglucose (154-17-6) + Sucrose (57-50-1) → 2-deoxy-maltose (58634-81-4,58634-82-5,132055-05-1,132055-06-2) + C60H102O50 + C54H92O45 + C48H82O40 + C42H72O35 + C36H62O30 + D-turanose (547-25-1) + 1-O-α-D-glucopyranosyl-β-D-fructose (51411-23-5)

Guidance literature:

With recombinant amylosucrase from Neisseriapolysaccharea; In aq. buffer; at 35 ℃; Enzymatic reaction;

DOI:10.1016/j.carbpol.2015.06.012

upstream raw materials:

D-Fructose

Sucrose

D-2-deoxyglucose

sulfuric acid

Downstream raw materials:

α-D-glucopyranosyl-(1->6)-D-gulitol

1-O-α-D-glucopyranosyl-D-mannitol

mannitol

D-sorbitol

Refernces

• 1、 Lee, Byung-Hoo,Koh, Dong-Wan,Territo, Paul R.,Park, Cheon-Seok,Hamaker, Bruce R.,Yoo, Sang-Ho. "Enzymatic synthesis of 2-deoxyglucose-containing maltooligosaccharides for tracing the location of glucose absorption from starch digestion". . p. 41 - 49. Retrieved 2015/07/07.