thiobenzoyl 2-(5,5-dimethyl-2-thiono-1,3,2-dioxaphosphorinanyl)sulfide

Base Information

• Chemical Name: thiobenzoyl 2-(5,5-dimethyl-2-thiono-1,3,2-dioxaphosphorinanyl)sulfide
• CAS No.: 463962-26-7
• Molecular Formula: C₁₂H₁₅O₂PS₃
• Molecular Weight: 318.422
• Mol file: 463962-26-7.mol

Synonyms:thiobenzoyl 2-(5,5-dimethyl-2-thiono-1,3,2-dioxaphosphorinanyl)sulfide

Chemical Property of thiobenzoyl 2-(5,5-dimethyl-2-thiono-1,3,2-dioxaphosphorinanyl)sulfide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of thiobenzoyl 2-(5,5-dimethyl-2-thiono-1,3,2-dioxaphosphorinanyl)sulfide

There total 7 articles about thiobenzoyl 2-(5,5-dimethyl-2-thiono-1,3,2-dioxaphosphorinanyl)sulfide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

benzoyl 2-(5,5-dimethyl-2-thiono-1,3,2-dioxaphosphorinanyl)sulfide (157841-96-8) → thiobenzoyl 2-(5,5-dimethyl-2-thiono-1,3,2-dioxaphosphorinanyl)sulfide (463962-26-7)

Guidance literature:

With 5,5-dimethyl-2-thiolo-2-thiono-1,3,2-dioxaphosphorinane; In benzene; for 2h; Heating;

DOI:10.1055/s-2002-31957

Reference yield:

5,5-dimethyl-2-thiolo-2-thiono-1,3,2-dioxaphosphorinane (697-45-0) → thiobenzoyl 2-(5,5-dimethyl-2-thiono-1,3,2-dioxaphosphorinanyl)sulfide (463962-26-7)

Guidance literature:

Multi-step reaction with 2 steps

1: 98 percent / Et₃N / benzene / 0.25 h

2: 94 percent / 5,5-dimethyl-2-thiolo-2-thiono-1,3,2-dioxaphosphorinane / benzene / 2 h / Heating

With 5,5-dimethyl-2-thiolo-2-thiono-1,3,2-dioxaphosphorinane; triethylamine; In benzene;

DOI:10.1055/s-2002-31957

Reference yield:

benzoyl chloride (98-88-4) → thiobenzoyl 2-(5,5-dimethyl-2-thiono-1,3,2-dioxaphosphorinanyl)sulfide (463962-26-7)

Guidance literature:

Multi-step reaction with 2 steps

1: 98 percent / pyridine / benzene / 0.25 h

2: 94 percent / 5,5-dimethyl-2-thiolo-2-thiono-1,3,2-dioxaphosphorinane / benzene / 2 h / Heating

With pyridine; 5,5-dimethyl-2-thiolo-2-thiono-1,3,2-dioxaphosphorinane; In benzene; 1: Acylation / 2: Thionation;

DOI:10.1039/b005911k

upstream raw materials:

benzoyl 2-(5,5-dimethyl-2-thiono-1,3,2-dioxaphosphorinanyl)sulfide

5,5-dimethyl-2-thiolo-2-thiono-1,3,2-dioxaphosphorinane

benzoyl chloride

1-benzoylimidazole

Downstream raw materials:

N-thiobenzoylpiperidine

N-isopropylthiobenzhydroxamic acid

N-hydroxy-N-methylbenzenecarbothioamide

5-phenyl-1,2,3,4-thiatriazole

Refernces

• 1、 Doszczak, Leszek,Rachon, Janusz. "Synthesis of S-thioacyl dithiophosphates, efficient and chemoselective thioacylating agents". . p. 1271 - 1279. Retrieved 2007/10/03.