Bis(m-phenoxyphenyl)ether

Base Information

• Chemical Name: Bis(m-phenoxyphenyl)ether
• CAS No.: 748-30-1
• Molecular Formula: C24H18O3
• Molecular Weight: 354.405
• NSC Number: 57093
• UNII: DP0504LMP7
• DSSTox Substance ID: DTXSID2061068
• Nikkaji Number: J421.527C
• Wikidata: Q81989299
• Mol file: 748-30-1.mol

Synonyms:Bis(m-phenoxyphenyl)ether;748-30-1;Ether, bis(m-phenoxyphenyl);Benzene, 1,1'-oxybis[3-phenoxy-;Benzene, 1,1'-oxybis(3-phenoxy-;bis(m-phenoxyphenyl) ether;DP0504LMP7;NSC 57093;NSC-57093;C24H18O3;NSC57093;m-phenoxyphenyl ether;bis(3-phenoxyphenyl) ether;UNII-DP0504LMP7;SCHEMBL380685;Benzene,1'-oxybis[3-phenoxy-;DTXSID2061068;1,1'-Oxybis(3-phenoxybenzene);Benzene, 1,1'-oxybis*3-phenoxy-;1-Phenoxy-3-(3-phenoxyphenoxy)benzene #;FT-0765484

Chemical Property of Bis(m-phenoxyphenyl)ether

Chemical Property:

• Boiling Point: 476oC at 760 mmHg
• Flash Point: 163.1oC
• PSA: 27.69000
• Density: 1.176g/cm3
• LogP: 7.06350
• XLogP3: 6.5
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 6
• Exact Mass: 354.125594432
• Heavy Atom Count: 27
• Complexity: 376

Purity/Quality:

99%, ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: C1=CC=C(C=C1)OC2=CC(=CC=C2)OC3=CC=CC(=C3)OC4=CC=CC=C4

Technology Process of Bis(m-phenoxyphenyl)ether

There total 4 articles about Bis(m-phenoxyphenyl)ether which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1-methoxy-3-phenoxybenzene (1655-68-1) → bis(m-phenoxyphenyl)ether (748-30-1)

Guidance literature:

Multi-step reaction with 2 steps

1: aq. HBr, AcOH, Ac₂O

2: (i) aq. KOH, (ii) /BRN= 1869631/, Cu, (heating)

With hydrogen bromide; acetic anhydride; acetic acid;

DOI:10.1021/jo01079a029

Reference yield:

3-phenoxyaniline (3586-12-7) → bis(m-phenoxyphenyl)ether (748-30-1)

Guidance literature:

Multi-step reaction with 2 steps

1: (i) (diazotization), (ii) CuBr, aq. HBr

2: (i) aq. KOH, (ii) /BRN= 1869631/, Cu, (heating)

DOI:10.1021/jo01079a029

Reference yield:

meta-phenoxyphenol (713-68-8) + 3-bromodiphenyl ether (6876-00-2) → bis(m-phenoxyphenyl)ether (748-30-1)

Guidance literature:

Multistep reaction; (i) aq. KOH, (ii) /BRN= 1869631/, Cu, (heating);

DOI:10.1021/jo01079a029

upstream raw materials:

meta-phenoxyphenol

3-bromodiphenyl ether

1-methoxy-3-phenoxybenzene

3-phenoxyaniline

Downstream raw materials:

recorcinol

benzene

phenol