Cava's dimer

Base Information

• Chemical Name: Cava's dimer
• CAS No.: 17509-84-1
• Molecular Formula: C₁₆H₁₂
• Molecular Weight: 204.271
• Mol file: 17509-84-1.mol

Synonyms:Cava's dimer

Chemical Property of Cava's dimer

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Cava's dimer

There total 5 articles about Cava's dimer which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 56.0%

C22H16 (139573-48-1) → Cava's dimer (17509-84-1) + anthracene (120-12-7) + 9,10-Dihydro-benzocyclobuteno<1',2';9,10>anthracen (7567-73-9)

Guidance literature:

In various solvent(s); at 223 ℃; Kinetics; Mechanism; other temperatures; log A, E_a, ΔG(excit.);

DOI:10.1016/0040-4039(92)88065-D

Reference yield: 4.0%

Tribenzo-Nenitzescu's hydrocarbon → Cava's dimer (17509-84-1) + anthracene (120-12-7) + dibenzo[a,e]cyclooctatetraene (262-89-5) + benz[a]anthracene (56-55-3)

Guidance literature:

at 600 ℃; under 1 Torr; Further byproducts given;

Reference yield:

spiro[cyclobutabenzene-1(2H),3'-diazirine] (299172-30-8) → Cava's dimer (17509-84-1) + phenylacetylene (536-74-3)

Guidance literature:

at 500 ℃; under 0.01 Torr; Title compound not separated from byproducts.;

DOI:10.1021/ja0039482

upstream raw materials:

dibenzo[a,e]cyclooctatetraene

C₂₂H₁₆

spiro[cyclobutabenzene-1(2H),3'-diazirine]

Downstream raw materials:

anthracene

dibenzo[a,e]cyclooctatetraene

9,10-dihydro-9,10-etheno-anthracene

benzobiphenylene

Refernces

• 1、 Banciu, Mircea D.,Stanescu, Michaela D.,Petride, Aurica,Parvulescu, Luminitza,Pop, Mircea. "Flow-Vacuum Pyrolysis of Polycyclic Compounds, 6. Pyrolysis of Dibenzo 8 Hydrocarbons". . p. 2513 - 2518. Retrieved 2007/10/02.
• 2、 Banciu, Mircea D.,Pop, Mircea,Petride, Aurica,Stanescu, Michaela Dina. "FLOW-VACUUM PYROLYSIS OF DIBENZOTRICYCLO2,5>-DECA-3,7,9-TRIENE (syn-DIBENZONENITZESCU'S HYDROCARBON) AND OF TRIBENZOTRICYCLO2,5>DECA-3,7,9-TRIENE (TRIBENZO-NENITZESCU'S HYDROCARBON)". . p. 907 - 916. Retrieved 2007/10/03.