Potassium;palladium(2+);tetrachloride

Base Information

• Chemical Name: Potassium;palladium(2+);tetrachloride
• CAS No.: 10025-98-6
• Molecular Formula: K2PdCl4
• Molecular Weight: 326.429
• Hs Code.: 28429080
• Mol file: 10025-98-6.mol

Synonyms:

Chemical Property of Potassium;palladium(2+);tetrachloride

Chemical Property:

• Appearance/Colour: reddish brown crystalline solid
• Vapor Pressure: 33900mmHg at 25°C
• Melting Point: 105 °C (dec.)(lit.)
• PSA: 0.00000
• Density: 2.67 g/mL at 25 °C(lit.)
• LogP: 2.75800
• Storage Temp.: 0-6°C
• Sensitive.: Hygroscopic
• Water Solubility.: SOLUBLE
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 0
• Exact Mass: 286.73965
• Heavy Atom Count: 6
• Complexity: 0

Purity/Quality:

99% ^*data from raw suppliers

Potassium tetrachloropalladate ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi
• Statements: 36/37/38-36/38
• Safety Statements: 26-36-37/39

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: [Cl-].[Cl-].[Cl-].[Cl-].[K+].[Pd+2]
• Uses: Potassium chloropalladite can be used in the synthesis of semiconducting metal-containing polymers in which the polypyrrole backbone has a conformational energy minimum and is nearly planar.1 Potassium tetrachloropalladate(II) is widely used as a reagent and as a source of palladium chloride to make other palladium complexes and palladium nanoparticles. It finds an application in the synthesis of semiconducting metal-containing polymers. It also reacts with bis(dithiolates) to form metal-bis(dithiolates), which is used in bar code material, laser Q-switch materials, optical CD recording media and superconductivity.

Technology Process of Potassium;palladium(2+);tetrachloride

There total 19 articles about Potassium;palladium(2+);tetrachloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

palladium dichloride → potassium tetrachloropalladate(II) (10025-98-6)

Guidance literature:

With KCl; In water; soln. of KCl and PdCl2 in min. amt. of water heated; crystd. on cooling;

Reference yield:

potassium chloride + ammonium chloride + palladium (7440-05-3) → potassium tetrachloropalladate(II) (10025-98-6)

Guidance literature:

With air or O₂; on heating of Pd with excess NH4Cl and KCl in presence of air or O2;;

Reference yield:

hydrogenchloride (7647-01-0,15364-23-5) + palladium (III) oxide hydrate + potassium chloride → potassium tetrachloropalladate(II) (10025-98-6)

Guidance literature:

In hydrogenchloride; detailed description given;;

upstream raw materials:

palladium

hydrogenchloride

chlorine

?Tyr

Downstream raw materials:

palladium

[N(C₄H₉)4]⁽¹⁺⁾*[PdBr(C₆F₅)2(P(C₆H₅)3)]^(1-)=[N(C₄H₉)4][PdBr(C₆F₅)2(P(C₆H₅)3)]

(NBu4)2{palladium(μ-Br)bis(pentafluorophenyl)}2

bis-triphenylphosphine-palladium(II) chloride

Refernces

• 1、 Tavman, Aydin,Hayvali, Mustafa,Filik, Hayati,Kili?, Emine. "Synthesis and characterization of polymeric Pd(II), Pt(IV), and Au(III) complexes of 2,2′-(1,4-phenylenedivinylene)-bis-8-hydroxyquinoline". . p. 1198 - 1201. Retrieved 2006.
• 2、 Aziz,Sirajuddin,Nadeem,Tirmizi,Khan,Munir,Ullah,Farooqi,Khan,Tahir. "Synthesis, crystal structure, antibacterial, cytotoxic, and anticancer activities of new Pd(II) complexes of tri-p-tolyl phosphine with thiones". . p. 2073 - 2082. Retrieved 2017.
• 3、 Moncada, Adriana I.,Manne, Sudhakar,Tanski, Joseph M.,Slaughter, LeGrande M.. "Modular chelated palladium diaminocarbene complexes: Synthesis, characterization, and optimization of catalytic Suzuki-Miyaura cross-coupling activity by ligand modification". . p. 491 - 505. Retrieved 2006.
• 4、 Patra, Shanti G.,Shee, Nirmal K.,Drew, Michael G. B.,Datta, Dipankar. "Palladium(II)-palladium(II) bonding in two open clamshell dinuclear complexes". . p. 7384 - 7391. Retrieved 2017.
• 5、 Gao, Enjun,Zhu, Mingchang,Liu, Lei,Huang, Yun,Wang, Lei,Shi, Chuyue,Zhang, Wanzhong,Sun, Yaguang. "Impact of the carbon chain length of novel palladium(ll) Complexes on interaction with DNA and cytotoxic activity". . p. 3261 - 3270. Retrieved 2010.
• 6、 Chakraborty, Jishnunil,Mayer-Figge, Heike,Sheldrick, William S.,Banerjee, Pradyot. "Self-assembly of [M(Hida)2] (Hida- = iminodiacetate; M = Pd and Pt) in a 2D supramolecular network via extensive hydrogen bonded interactions: Synthesis, X-ray crystal structure, spectroscopic and thermal studies". . p. 771 - 776. Retrieved 2005.
• 7、 Tanino,Kobayashi. "OPTICAL SPECTRA OF PALLADIUM CHLORIDE.". . p. 3978 - 3984. Retrieved 1983.
• 8、 Rotondo, Archimede,Barresi, Salvatore,Cusumano, Matteo,Rotondo, Enrico. "Structural and dynamic NMR characterization of [Pd(bipy)(R-thiourea) 2]2+ and [Pd(phen)(R-thiourea)2]2+ cations". . p. 23 - 29. Retrieved 2012.
• 9、 Torgov,Kostin,Mashukov,Korda,Drapailo,Kas'Yan,Kal'Chenko. "Palladium(II) extraction by sulfur-containing calix[4,6]arenes from hydrochloric acid solutions". . p. 1809 - 1815. Retrieved 2008.
• 10、 Sadaf, Haseeba,Imtiaz-ud-Din,Zahra, Syeda Saniya,Ihsan-ul-Haq,Nadeem, Shafqat,Tahir, Muhammad Nawaz,Ahmad, Saeed,Andleeb, Sohaila. "Synthesis, X-ray structures and biological properties of palladium(II) complexes of 1,2-dimethylimidazole and benzimidazole". . p. 101 - 107. Retrieved 2019.