Allyl 10-undecenoate

Base Information

• Chemical Name: Allyl 10-undecenoate
• CAS No.: 7493-76-7
• Molecular Formula: C14H24 O2
• Molecular Weight: 224.343
• Hs Code.: 2916190090
• European Community (EC) Number: 231-337-3
• NSC Number: 62647
• UNII: QM7A7RN7O9
• DSSTox Substance ID: DTXSID8064723
• Nikkaji Number: J307.836A
• Wikidata: Q27287332
• Metabolomics Workbench ID: 47344
• Mol file: 7493-76-7.mol

Synonyms:Allyl undecylenate;7493-76-7;ALLYL 10-UNDECENOATE;10-Undecenoic acid, 2-propenyl ester;Allyl undec-10-enoate;prop-2-enyl undec-10-enoate;10-Undecenoic acid, allyl ester;2-Propenyl 10-undecenoate;10-Undecenoic acid,2-propen-1-yl ester;FEMA No. 2044;prop-2-en-1-yl undec-10-enoate;UNII-QM7A7RN7O9;QM7A7RN7O9;10-Undecenoic acid, 2-propen-1-yl ester;EINECS 231-337-3;NSC 62647;NSC-62647;AI3-22365;Allyl-undecylenate;SCHEMBL3505629;10-Undecenoic acid allyl ester;DTXSID8064723;CHEBI:171789;NSC62647;ALLYL 10-UNDECENOATE [FHFI];LMFA07010780;MFCD00048190;10-Undecenoic acid, allyl ester (8CI);FT-0636506;Q27287332

Chemical Property of Allyl 10-undecenoate

Chemical Property:

• Vapor Pressure: 0.00202mmHg at 25°C
• Boiling Point: 290.9oC at 760 mmHg
• Flash Point: 93.4oC
• PSA: 26.30000
• Density: 0.885g/cm3
• LogP: 4.02240
• XLogP3: 4.8
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 12
• Exact Mass: 224.177630004
• Heavy Atom Count: 16
• Complexity: 197

Purity/Quality:

99% ^*data from raw suppliers

allyl 10-undecenoate AldrichCPR ^*data from reagent suppliers

Safty Information:

• Statements: 36/37/38
• Safety Statements: 26-36/37/39

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C=CCCCCCCCCC(=O)OCC=C

Technology Process of Allyl 10-undecenoate

There total 5 articles about Allyl 10-undecenoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

phenyl 10-undecenoate (18508-59-3) + allyl alcohol (107-18-6) → allyl 10-undec-10-enoate (7493-76-7)

Guidance literature:

With 1,3,4,6,7,8-hexahydro-2H-pyrimido[1,2-a]pyrimidine; In neat (no solvent); at 140 ℃; for 1h; Microwave irradiation; Green chemistry;

DOI:10.1039/c5ra10206e

Reference yield:

10-undecenoic acid (112-38-9) + allyl alcohol (107-18-6) → allyl 10-undec-10-enoate (7493-76-7)

Guidance literature:

With naphthalene-2-sulfonate; benzene; azeotrope Destillation;

DOI:10.1021/ja01175a037

Reference yield:

C13H22O3 + methyl-triphenylphosphonium iodide (2065-66-9) → allyl 10-undec-10-enoate (7493-76-7)

Guidance literature:

With potassium tert-butylate; In benzene; at 20 ℃; Inert atmosphere; Reflux;

DOI:10.1021/ol401426p

upstream raw materials:

10-undecenoic acid

allyl alcohol

methyl-triphenylphosphonium iodide

phenyl 10-undecenoate

Downstream raw materials:

10-undecenoic acid

Refernces

• 1、 Maity, Soham,Manna, Srimanta,Rana, Sujoy,Naveen, Togati,Mallick, Arijit,Maiti, Debabrata. "Efficient and stereoselective nitration of mono- and disubstituted olefins with AgNO2 and TEMPO". supporting information. p. 3355 - 3358. Retrieved 2013/04/10.