Technology Process of Acetylene, 1-phenyl-2-trimethylgermyl-
There total 4 articles about Acetylene, 1-phenyl-2-trimethylgermyl- which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
With
[{Ir(μ-Cl)(CO)2}2]; N-ethyl-N,N-diisopropylamine;
In
toluene;
at 80 ℃;
for 24h;
Schlenk technique;
Inert atmosphere;
Sealed tube;
DOI:10.1039/c4dt02290d
- Guidance literature:
-
With
methylmagnesium bromide;
In
diethyl ether;
(Ar); drop a soln. of MeMgBr to a soln. of educt at 0°C; stirring for 30 min at 0°C and then for 3 h at 20°C; evapn. of solvent (vac.); distn. (vac.);
DOI:10.1016/0022-328X(89)85019-3
- Guidance literature:
-
With
18-crown-6 ether;
cesium fluoride;
In
benzene;
(Ar); addn. of CsF to a mixt. of phenylacetylene and 18-crown-6 in C6H6,stirring for 5 min, addn. of germanium compd., stirring at room temp. f or 5-7 h; filtration through SiO2 or Al2O3, evapn.;
DOI:10.1016/S0022-328X(01)01109-3