2-ethylhexyl bromoacetate

Base Information

• Chemical Name: 2-ethylhexyl bromoacetate
• CAS No.: 68144-73-0
• Molecular Formula: C10H19BrO2
• Molecular Weight: 251.164
• Mol file: 68144-73-0.mol

Synonyms:

Chemical Property of 2-ethylhexyl bromoacetate

Chemical Property:

• Vapor Pressure: 0.0327mmHg at 25°C
• Boiling Point: 243.1°C at 760 mmHg
• Flash Point: 112.1°C
• Density: 1.192g/cm³

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 2-ethylhexyl bromoacetate

There total 1 articles about 2-ethylhexyl bromoacetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

2-Ethylhexyl alcohol (104-76-7) + bromoacetic acid (79-08-3) → bromoacetic acid 2-ethylhexyl ester (68144-73-0)

Guidance literature:

With toluene-4-sulfonic acid; In toluene; for 18h; Heating;

DOI:10.1248/cpb.56.369

Reference yield: 55.0%

bromoacetic acid 2-ethylhexyl ester (68144-73-0) + (E)-3-phenyl-6-(4'-diphenylaminostilben-4-yl)pyrrolo[3,4-c]pyrrole-1,4(2H,5H)-dione (1602949-94-9) → (E)-bis(2-ethylhexyl) 2,2′-(3-{4-[4-(diphenylamino)styryl]phenyl})-1,4-dioxo-6-phenylpyrrolo[3,4-c]pyrrole-2,5-(1H,4H)-diyl diacetate (1602949-97-2)

Guidance literature:

With potassium carbonate; In N,N-dimethyl-formamide; at 120 ℃; for 2h;

DOI:10.1016/j.tetlet.2014.03.080

Reference yield: 30.0%

bromoacetic acid 2-ethylhexyl ester (68144-73-0) + triphenylphosphine (603-35-0) → 2-ethylhexyloxycarbonylmethyltriphenylphosphonium bromide (1040109-26-9)

Guidance literature:

In toluene; at 20 ℃; for 4h;

DOI:10.1248/cpb.56.369

upstream raw materials:

2-Ethylhexyl alcohol

bromoacetic acid

Downstream raw materials:

2-ethylhexyloxycarbonylmethyltriphenylphosphonium bromide

bis(2-ethylhexyl) 2,2'-(3,6-bis-(E)-{4-[4-(diphenylamino)styryl]phenyl})-1,4-dioxopyrrolo[3,4-c]pyrrole-2,5-(1H,4H)-diyl diacetate

(E)-bis(2-ethylhexyl) 2,2′-(3-{4-[4-(diphenylamino)styryl]phenyl})-1,4-dioxo-6-phenylpyrrolo[3,4-c]pyrrole-2,5-(1H,4H)-diyl diacetate

Refernces

• 1、 Chiang, Chih-Chia,Chang, Tsu-Chung,Tsai, Hou-Jen,Hsu, Ling-Yih. "Synthesis and biological evaluation of sulfur-containing cinnamate and salicylate derivatives". . p. 369 - 373. Retrieved 2008/09/20.