cis 1H,2H/1,2-bis(trifluoromethyl)octafluorocyclohexane

Base Information

• Chemical Name: cis 1H,2H/1,2-bis(trifluoromethyl)octafluorocyclohexane
• CAS No.: 110897-06-8
• Molecular Formula: C₈H₂F₁₄
• Molecular Weight: 364.082
• Mol file: 110897-06-8.mol

Synonyms:cis 1H,2H/1,2-bis(trifluoromethyl)octafluorocyclohexane

Chemical Property of cis 1H,2H/1,2-bis(trifluoromethyl)octafluorocyclohexane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of cis 1H,2H/1,2-bis(trifluoromethyl)octafluorocyclohexane

There total 1 articles about cis 1H,2H/1,2-bis(trifluoromethyl)octafluorocyclohexane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1,2-bis(trifluoromethyl)-3,3,4,4,5,5,6,6-octafluorocyclohexene (10534-39-1) → 6H-1,6-bis(trifluoromethyl)heptafluorocyclohexene (110897-05-7) + cis 1H,2H/1,2-bis(trifluoromethyl)octafluorocyclohexane (110897-06-8)

Guidance literature:

With hydrogen; palladium on activated charcoal; at 16 ℃; for 24h; under 76000 Torr;

DOI:10.1016/S0022-1139(00)81941-7

Reference yield:

cis 1H,2H/1,2-bis(trifluoromethyl)octafluorocyclohexane (110897-06-8) → 1,2-bis(trifluoromethyl)decafluorocyclohexane (306-98-9) + trans 1H-2-trifluoromethyl/-1-trifluoromethylnonafluorocyclohexane + cis 1H-1,2-bis-(trifluoromethyl)nonafluorocyclohexane

Guidance literature:

With cobalt(III) fluoride; at 215 ℃;

DOI:10.1016/S0022-1139(00)81941-7

Reference yield:

cis 1H,2H/1,2-bis(trifluoromethyl)octafluorocyclohexane (110897-06-8) → 1,2-bis(trifluoromethyl)-3,3,4,4,5,5,6,6-octafluorocyclohexene (10534-39-1)

Guidance literature:

Multi-step reaction with 2 steps

1: 1.0 g / cobalt(III) fluoride / 215 °C

2: 0.02 h / in presence of KOH in D₂O; dehydrofluorination; effect of time

With cobalt(III) fluoride;

DOI:10.1016/S0022-1139(00)81941-7

upstream raw materials:

1,2-bis(trifluoromethyl)-3,3,4,4,5,5,6,6-octafluorocyclohexene

Downstream raw materials:

1,2-bis(trifluoromethyl)decafluorocyclohexane

2,3-bis(trifluoromethyl)hexafluorocyclohexa-1,3-diene

6H-1,6-bis(trifluoromethyl)heptafluorocyclohexene

1,2-bis(trifluoromethyl)-3,3,4,4,5,5,6,6-octafluorocyclohexene

Refernces