1,5-Diphenylcarbazone

Base Information

• Chemical Name: 1,5-Diphenylcarbazone
• CAS No.: 538-62-5
• Deprecated CAS: 15102-05-3
• Molecular Formula: C13H12N4O
• Molecular Weight: 240.264
• Hs Code.: 29280000
• European Community (EC) Number: 208-698-0
• UNII: 5UYJ4R0D5T,96YS88318X
• DSSTox Substance ID: DTXSID5060225
• Nikkaji Number: J82.129B
• Wikipedia: Diphenylcarbazone
• Wikidata: Q1227136,Q27271938
• ChEMBL ID: CHEMBL79409
• Mol file: 538-62-5.mol

Synonyms:diphenylcarbazone

Chemical Property of 1,5-Diphenylcarbazone

Chemical Property:

• Appearance/Colour: Orange powder
• Melting Point: 119-123 °C(lit.)
• Refractive Index: 1.617
• Boiling Point: 382.98°C (rough estimate)
• PKA: 9.83±0.43(Predicted)
• PSA: 65.85000
• Density: 1.19 g/cm³
• LogP: 3.97090
• Storage Temp.: 2-8°C
• Solubility.: DMSO (Slightly), Methanol (Slightly)
• Water Solubility.: Soluble in acetone. Insoluble in water.
• XLogP3: 3.6
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 3
• Exact Mass: 240.10111102
• Heavy Atom Count: 18
• Complexity: 281

Purity/Quality:

99% ^*data from raw suppliers

1,5-DiphenylcarbazoneCompoundWith1,5-Diphenylcarbazide ^*data from reagent suppliers

Safty Information:

• Statements: 22-36/37/38
• Safety Statements: 22-24/25-36/37/39-26

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Chemical Classes: Nitrogen Compounds -> Hydrazides
• Canonical SMILES: C1=CC=C(C=C1)NNC(=O)N=NC2=CC=CC=C2
• Uses: Indicator As a sensitive reagent for Hg, with which it gives a blue color. It is a reagent for mercury determination.

Technology Process of 1,5-Diphenylcarbazone

There total 11 articles about 1,5-Diphenylcarbazone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

1,5-diphenyl-thiocarbazone (60-10-6) → diphenylcarbazone (538-62-5)

Guidance literature:

With Oxone; for 0.333333h;

DOI:10.1081/SCC-120016359

Reference yield: 95.0%

1,5-diphenylcarbazide (140-22-7) → diphenylcarbazone (538-62-5)

Guidance literature:

With sodium hydrogen sulfate; silica gel; sodium nitrite; In dichloromethane; at 20 ℃;

Reference yield:

→ diphenylcarbazone (538-62-5)

Guidance literature:

With sulfuric acid;

upstream raw materials:

1,5-diphenyl-thiocarbazone

1,5-diphenylcarbazide

benzoin oxime

Downstream raw materials:

1-phenoxaborin-10-yl-1,5-diphenyl-carbazone

1,5-diphenylcarbazide

benzoin oxime

Refernces

• 1、 Zou, Mingming,Kong, Yumei,Wang, Jun,Wang, Qi,Wang, Zhiqiu,Wang, Baoxin,Fan, Ping. "Spectroscopic analyses on ROS generation catalyzed by TiO2, CeO2/TiO2 and Fe2O3/TiO2 under ultrasonic and visible-light irradiation". . p. 82 - 90. Retrieved 2013.
• 2、 He, Ling-Ling,Wang, Xin,Wu, Xiao-Xia,Wang, Yong-Xia,Kong, Yu-Mei,Wang, Xin,Liu, Bing-Mi,Liu, Bin. "Protein damage and reactive oxygen species generation induced by the synergistic effects of ultrasound and methylene blue". . p. 361 - 366. Retrieved 2015.
• 3、 Wang, Yulu,Shi, Lei,Jia, Xueshun,Pan, Feng,Ma, Donglan,Wang, Xiaoyang. "An efficient and convenient procedure for preparation of diaryl carbazone from aryl substituted carbazide". . p. 53 - 56. Retrieved 1999.
• 4、 Zhu, Lei,Oh, Won-Chun. "Bubble template synthesis of CdLa2S4 hollow spheres/reduced graphene oxide nanocomposites as efficient and sustainable visible-light driven photocatalysts". . p. 90321 - 90334. Retrieved 2015/11/11.