Benzenesulfonamide, N-(phenylsulfonyl)-, sodium salt

Base Information

• Chemical Name: Benzenesulfonamide, N-(phenylsulfonyl)-, sodium salt
• CAS No.: 2532-07-2
• Deprecated CAS: 1809540-24-6,2243741-41-3
• Molecular Formula: C12H11 N O4 S2 . Na
• Molecular Weight: 319.337
• European Community (EC) Number: 219-792-6
• DSSTox Substance ID: DTXSID3062499
• Nikkaji Number: J76.681J
• Mol file: 2532-07-2.mol

Synonyms:2532-07-2;Dibenzenesulfonamide, sodium salt;Benzenesulfonamide, N-(phenylsulfonyl)-, sodium salt;Benzenesulfonamide, N-(phenylsulfonyl)-, sodium salt (1:1);Bis(phenylsulfonyl)aminosodium;DTXSID3062499;EINECS 219-792-6;NSC 49219;Sodium N-(phenylsulphonyl)benzenesulphonamidate

Chemical Property of Benzenesulfonamide, N-(phenylsulfonyl)-, sodium salt

Chemical Property:

• Vapor Pressure: 2.13E-09mmHg at 25°C
• Boiling Point: 480.6°Cat760mmHg
• Flash Point: 244.5°C
• PSA: 97.07000
• Density: g/cm³
• LogP: 3.90630
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 5
• Rotatable Bond Count: 4
• Exact Mass: 318.99489443
• Heavy Atom Count: 20
• Complexity: 435

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)S(=O)(=O)[N-]S(=O)(=O)C2=CC=CC=C2.[Na+]

Technology Process of Benzenesulfonamide, N-(phenylsulfonyl)-, sodium salt

There total 1 articles about Benzenesulfonamide, N-(phenylsulfonyl)-, sodium salt which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

dibenzenesulfonamide (2618-96-4) → bisphenylsulfonylimide sodium salt (2532-07-2)

Guidance literature:

With sodium hydroxide; In water;

DOI:10.1021/jacs.6b11533

Reference yield: 100.0%

bisphenylsulfonylimide sodium salt (2532-07-2) → N-nitrobenzenesulfonimide (80284-04-4)

Guidance literature:

With nitronium tetrafluoborate; In dichloromethane; at -30 ℃; for 0.5h;

DOI:10.1007/BF00949479

Reference yield: 79.0%

1-(chloromethyl)-4-aza-1-azoniabicyclo[2.2.2]octane chloride (36273-11-7) + bisphenylsulfonylimide sodium salt (2532-07-2) → 1-(chloromethyl)-1,4-diazabicyclo[2.2.2]octan-1-ium N',N'-bisbenzenesulfonylimide salt

Guidance literature:

In acetonitrile;

DOI:10.1002/cjoc.201400680

upstream raw materials:

dibenzenesulfonamide

Downstream raw materials:

N,N-Dibenzolsulfonyl-glycin-aethylester

N-(4-Chlor-phenacyl)-dibenzolsulfonamid

N-nitrobenzenesulfonimide

Refernces

• 1、 -. "N-sulfur aryl benzenesulfonyl imide and preparation method and application thereof". Paragraph 0031; 0034-0036; 0038-0040; 0042-0044; 0046-0047. . Retrieved 2020/11/12.
• 2、 Buckingham, Faye,Kirjavainen, Anna K.,Forsback, Sarita,Krzyczmonik, Anna,Keller, Thomas,Newington, Ian M.,Glaser, Matthias,Luthra, Sajinder K.,Solin, Olof,Gouverneur, Véronique. "Organomediated Enantioselective 18F Fluorination for PET Applications". supporting information. p. 13366 - 13369. Retrieved 2015/11/09.