[Cp*Ir(η3-CH2CHCHPh)(PPh3)]OTf

Base Information

• Chemical Name: [Cp*Ir(η3-CH2CHCHPh)(PPh3)]OTf
• CAS No.: 260783-60-6
• Molecular Formula: CF₃O₃S*C₃₇H₃₉IrP
• Molecular Weight: 855.981
• Mol file: 260783-60-6.mol

Synonyms:[Cp*Ir(η3-CH2CHCHPh)(PPh3)]OTf

Chemical Property of [Cp*Ir(η3-CH2CHCHPh)(PPh3)]OTf

Chemical Property:

Purity/Quality:

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Technology Process of [Cp*Ir(η3-CH2CHCHPh)(PPh3)]OTf

There total 5 articles about [Cp*Ir(η3-CH2CHCHPh)(PPh3)]OTf which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

[Cp*Ir(η3-CH2CHCHPh)(NH=C(NMe2)Me)]OTf (260783-66-2) + triphenylphosphine (603-35-0) → [Cp*Ir(η3-CH2CHCHPh)(PPh3)]OTf (260783-60-6) + N,N-dimethylacetamidine (2909-14-0)

Guidance literature:

In tetrahydrofuran-d8; PPh3 was added to THF-d8 soln. (Cp*Ir(η3-CH2CHCHPh)(NH=C(NMe2)Me))OTf and react. mixt. was refluxed for 12 h; react. mixt. was cooled to room temp., volatiles were removed, residue was washed with Et2O; elem. anal.;

DOI:10.1021/om9908480

Reference yield: 86.0%

[Cp*Ir(η3-CH2CHCHPh)(NH=C(NHMe)Me)]OTf (260783-68-4) + triphenylphosphine (603-35-0) → methyl N-methylacetamidate (44201-67-4) + [Cp*Ir(η3-CH2CHCHPh)(PPh3)]OTf (260783-60-6)

Guidance literature:

In tetrahydrofuran-d8; PPh3 was added to THF-d8 soln. (Cp*Ir(η3-CH2CHCHPh)(NH=C(NHMe)Me))OTf and react. mixt. was refluxed for 12 h; react. mixt. was cooled to room temp., volatiles were removed, residue was washed with Et2O; elem. anal.;

DOI:10.1021/om9908480

Reference yield: 82.0%

[Cp*Ir(η3-CH2CHCHPh)(NH=C(OMe)Me)]OTf (260783-86-6,261158-77-4) + triphenylphosphine (603-35-0) → methyl acetimidate (14777-29-8,85273-25-2) + [Cp*Ir(η3-CH2CHCHPh)(PPh3)]OTf (260783-60-6)

Guidance literature:

In tetrahydrofuran-d8; PPh3 was added to THF-d8 soln. (Cp*Ir(η3-CH2CHCHPh)(NH=C(OMe)Me))OTf and react. mixt. was refluxed for 12 h; react. mixt. was cooled to room temp., volatiles were removed, residue was washed with Et2O; elem. anal.;

DOI:10.1021/om9908480

upstream raw materials:

[Cp*Ir(η3-CH2CHCHPh)(NH=C(O-i-Pr)Me)]OTf

triphenylphosphine

[Cp*Ir(η3-CH2CHCHPh)(NH=C(NMe2)Me)]OTf

[Cp*Ir(η3-CH2CHCHPh)(NH=C(OMe)Me)]OTf

Refernces