Benzo[c]chrysene

Base Information

• Chemical Name: Benzo[c]chrysene
• CAS No.: 194-69-4
• Molecular Formula: C22H14
• Molecular Weight: 278.353
• Hs Code.: 2902909090
• European Community (EC) Number: 681-927-3
• UNII: 0I8Z8V58Z4
• DSSTox Substance ID: DTXSID3073894
• Nikkaji Number: J35.609C
• Wikidata: Q27236814
• Mol file: 194-69-4.mol

Synonyms:1,2,5,6-dibenzphenanthrene;1,2:5,6-dibenzophenanthrene;benzo(c)chrysene

Chemical Property of Benzo[c]chrysene

Chemical Property:

• Vapor Pressure: 1.41E-10mmHg at 25°C
• Melting Point: 126.5°C
• Refractive Index: 1.8120 (estimate)
• Boiling Point: 524.7°Cat760mmHg
• Flash Point: 264.5°C
• PSA: 0.00000
• Density: 1.232g/cm³
• LogP: 6.29940
• Storage Temp.: 2-8°C
• XLogP3: 7
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 0
• Exact Mass: 278.109550447
• Heavy Atom Count: 22
• Complexity: 399

Purity/Quality:

98%,99%, ^*data from raw suppliers

Benzo[c]chrysene BCR ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Chemical Classes: Other Classes -> Polycyclic Aromatic Hydrocarbons
• Canonical SMILES: C1=CC=C2C(=C1)C=CC3=C2C=CC4=C3C5=CC=CC=C5C=C4

Technology Process of Benzo[c]chrysene

There total 22 articles about Benzo[c]chrysene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

trans-1-(1-naphthyl)-2-(2-naphthyl)ethylene (2633-11-6) → benzo[c]chrysene (194-69-4)

Guidance literature:

With iodine; methyloxirane; In benzene; for 1h; Irradiation;

DOI:10.1021/jo00012a005

Reference yield: 96.0%

(E)-2-styryl-[1,2'-binaphthalene]-1'-carbaldehyde → benzo[c]chrysene (194-69-4)

Guidance literature:

With iron(III) chloride; In 1,2-dichloro-ethane; at 20 ℃; for 12h; regioselective reaction;

DOI:10.1021/jacs.7b01114

Reference yield: 95.0%

C22H18 → benzo[c]chrysene (194-69-4)

Guidance literature:

With trityl tetrafluoroborate; In 1,2-dichloro-ethane; for 3h; Reflux;

DOI:10.1246/bcsj.20190252

upstream raw materials:

4-phenethyl-1,2-dihydro-phenanthrene

trans-4-Styrylphenanthrene

trans-2-Styrylphenanthren

(E,E)-1,3-distyrylbenzene

Refernces

• 1、 McAtee, Christopher C.,Riehl, Paul S.,Schindler, Corinna S.. "Polycyclic Aromatic Hydrocarbons via Iron(III)-Catalyzed Carbonyl-Olefin Metathesis". supporting information. p. 2960 - 2963. Retrieved 2017/03/11.
• 2、 Liu, Longbin,Yang, Bingwei,Katz, Thomas J.,Poindexter, Michael K.. "Improved Methodology for Photocyclization Reactions". . p. 3769 - 3775. Retrieved 2007/10/02.