CIS-DECAHYDRONAPHTHALENE

Base Information

• Chemical Name: CIS-DECAHYDRONAPHTHALENE
• CAS No.: 493-01-6
• Molecular Formula: C10H18
• Molecular Weight: 138.253
• Hs Code.: 29021990
• Mol file: 493-01-6.mol

Synonyms:cis-Bicyclo[4.4.0]decane;cis-Decahydronaphthalene; cis-Decalin; cis-Perhydronaphthalene

Chemical Property of CIS-DECAHYDRONAPHTHALENE

Chemical Property:

• Appearance/Colour: colourless liquid
• Vapor Pressure: 42 mm Hg ( 92 °C)
• Melting Point: −43 °C(lit.)
• Refractive Index: n20/D 1.481(lit.)
• Boiling Point: 193 °C(lit.)
• Flash Point: 57.2°C
• PSA: 0.00000
• Density: 0.872g/cm³
• LogP: 3.36680
• Storage Temp.: Sealed in dry,Room Temperature
• Water Solubility.: 6 mg/L at 20℃

Purity/Quality:

98%, ^*data from raw suppliers

cis-Decahydronaphthalene >98.0%(GC) ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xn,N,C
• Statements: 20-36/37/38-65-51/53-34
• Safety Statements: 26-36-62-61-45-36/37/39

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Uses: cis-Decahydronaphthalene is used as a quantitation standard in the determination of sesquiterpanes.

Technology Process of CIS-DECAHYDRONAPHTHALENE

There total 74 articles about CIS-DECAHYDRONAPHTHALENE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

1,2,3,4,5,6,7,8-octahydro-naphthalene (493-03-8) → Cyclooctan (292-64-8) + cis-decalin (493-01-6) + trans-Decalin (493-02-7)

Guidance literature:

With cis-Cyclooctene; ammonium hypophosphorous acid; palladium on activated charcoal; for 4h;

Reference yield: 95.0%

naphthalene (91-20-3,71998-51-1,72931-45-4) → tetralin (119-64-2) + cis-decalin (493-01-6) + trans-Decalin (493-02-7)

Guidance literature:

With hydrogen; lithium aluminium tetrahydride; titanium(III) chloride; In hexane; at 200 ℃; for 15h; under 67505.4 Torr; Yields of byproduct given;

Reference yield: 58.0%

cis-Cyclooctene (931-88-4,931-87-3,25267-51-0) → Cyclooctan (292-64-8) + cis-decalin (493-01-6) + trans-Decalin (493-02-7)

Guidance literature:

With ammonium hypophosphorous acid; Δ^9,10-octaline; palladium on activated charcoal; for 4h;

upstream raw materials:

5,6,7,8-Tetrahydro-2-naphthol

naphthalene

tetralin

cis-2,3-octalin

Downstream raw materials:

trans-Decalin

trans-octahydro-[4a]naphthyl hydroperoxide

1-acetoxy-11-oxa-bicyclo[4.4.1]undecane

pyridine

Refernces

• 1、 Vargas-Villagrán,Ramírez-Suárez,Ramírez-Mu?oz,Calzada,González-García,Klimova. "Tuning of activity and selectivity of Ni/(Al)SBA-15 catalysts in naphthalene hydrogenation". . p. 27 - 37. Retrieved 2021.
• 2、 Hiyoshi, Norihito,Mine, Eiichi,Rode, Chandrashekhar V.,Sato, Osamu,Shirai, Masayuki. "Stereoselective hydrogenation of tetralin to cis-decalin over a carbon-supported rhodium catalyst in supercritical carbon dioxide solvent". . p. 188 - 189. Retrieved 2006.
• 3、 Téllez-Romero,Cuevas-García,Ramírez,Castillo-Villalón,Contreras-Bárbara,Salcedo-Luna,Puente-Lee. "Simultaneous naphthalene and thiophene hydrogenation over Ni(X)-Pt/HMOR catalysts". . p. 12 - 20. Retrieved 2015.
• 4、 Bhattacharya, Saurav,Bons, Anton-Jan,Cadot, Emmanuel,Espenship, Michael Forrester,Haouas, Mohamed,Jaensch, Helge,Kortz, Ulrich,Laskin, Julia,Ma, Xiang,Mougharbel, Ali S.,Stuerzer, Tobias,Su, Pei,Taffa, Dereje H.,Wark, Michael. "Discovery of a Neutral 40-PdII-Oxo Molecular Disk, [Pd40O24(OH)16{(CH3)2AsO2}16]: Synthesis, Structural Characterization, and Catalytic Studies". . p. 17339 - 17347. Retrieved 2021/11/17.