Boron trifluoride dimethyl etherate

Base Information

• Chemical Name: Boron trifluoride dimethyl etherate
• CAS No.: 353-42-4
• Molecular Formula: C2H6BF3O
• Molecular Weight: 113.875
• Hs Code.: 29319090
• European Community (EC) Number: 206-532-1
• UN Number: 2965
• Wikidata: Q72451129
• Mol file: 353-42-4.mol

Synonyms:353-42-4;Boron trifluoride dimethyl etherate;Boron trifluoride methyl etherate;dimethyloxonio(trifluoro)boranuide;(dimethyloxonio)trifluoroborate;FOWZWMGLMYVYDH-UHFFFAOYSA-N;MFCD00013192;AKOS015916108;FT-0632018

Chemical Property of Boron trifluoride dimethyl etherate

Chemical Property:

• Appearance/Colour: clear brownish liquid, fuming in moist air
• Vapor Pressure: 2.99hPa at 20℃
• Melting Point: -14 °C
• Refractive Index: n20/D 1.308(lit.)
• Boiling Point: 126-127 °C(lit.)
• Flash Point: 96 °F
• PSA: 17.07000
• Density: 1.239 g/mL at 25 °C(lit.)
• LogP: 1.14240
• Storage Temp.: water-free area
• Water Solubility.: reacts
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 0
• Exact Mass: 114.0463795
• Heavy Atom Count: 7
• Complexity: 24.1
• Transport DOT Label: Dangerous When Wet Corrosive Flammable Liquid

Purity/Quality:

99% ^*data from raw suppliers

Boron trifluoride methyl etherate ^*data from reagent suppliers

Safty Information:

• Pictogram(s): F,C,T
• Hazard Codes: F,C,T
• Statements: 14/15-34-48/23-20/22
• Safety Statements: 16-26-28-36/37/39-45-8-43-28A-23

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Chemical Classes: Metals -> Metalloid Compounds (Boron)
• Canonical SMILES: B(F)(F)F.COC
• Uses: Reactant or reagent involved in:Deconvoluting the chemical reaction kinetics of platinum-silver ligand exchangeSynthesis of neurogenic ganglioside LLG-3 from starfish via glycosylation reactionsSynthesis of peloruside via lactonization and relay ring-closing metathesis cyclizationFRET for monitoring Pd-catalyzed nucleophilic allylic substitution reactionsSingle molecuel imaging of fluorophore-tagged palldium(II) complexesβ-elimination and rearrangement reactions for synthesis of exocyclic vinyl ethers

Technology Process of Boron trifluoride dimethyl etherate

There total 7 articles about Boron trifluoride dimethyl etherate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

boron trifluoride (7637-07-2) → fluorodimethoxyborane (367-46-4) + methyl difluoroborinate (381-59-9) + boron trifluoride dimethyl etherate (353-42-4)

Guidance literature:

With methanol;

Reference yield:

Dimethyl ether (115-10-6,157621-61-9) + boron trifluoride (7637-07-2) → boron trifluoride dimethyl etherate (353-42-4)

Guidance literature:

condensing with liq. N2;

DOI:10.1021/ja01263a009

Reference yield:

methanol (67-56-1) → boron trifluoride dimethyl etherate (353-42-4)

Guidance literature:

With boron trifluoride;

upstream raw materials:

methanol

Dimethyl ether

boron trifluoride

carbonic acid dimethyl ester

Downstream raw materials:

methylene chloride

Trimethyl borate

Dimethyl ether

tetramethylammonium tetrafluoroborate

Refernces

• 1、 Nxumalo, Lawrence M.,Ford, Thomas A.. "The Fourier transform infrared spectra of the complexes of boron trifluoride with dimethyl ether and dimethyl sulphide in cryogenic matrices". . p. 303 - 319. Retrieved 2003.
• 2、 Borchardt, D. B.,Saito, K.,Bauer, S. H.. "RELAXATION KINETICS IN GASEOUS LEWIS ACID/BASE SYSTEMS: THE PROTOTYPE, (CH3)2O+BF3". . p. 375 - 382. Retrieved 1990.
• 3、 -. "Monohydrater cefotiam hydrochloride compound and pharmaceutical composition thereof". Paragraph 0039; 0042; 0051; 0060. . Retrieved 2019/01/23.