Methyl trithion

Base Information

• Chemical Name: Methyl trithion
• CAS No.: 953-17-3
• Molecular Formula: C₉H₁₂ClO₂PS₃
• Molecular Weight: 314.818
• Hs Code.: 2931900090
• NSC Number: 231692
• UNII: X08H286BAN
• DSSTox Substance ID: DTXSID3040275
• Nikkaji Number: J7.188I
• Wikidata: Q27293162
• Mol file: 953-17-3.mol

Synonyms:METHYL TRITHION;Carbophenothion-methyl;Methyl Carbophenothion;953-17-3;Carbophenothion methyl;Trithion-methyl;Tri-Me;Geigy G-29288;Methylcarbophenothion;Methyltrithion;Stauffer R-1492;Caswell No. 212;ENT 25,599;ENT 25586;R-1492;NSC 231692;O,O-Dimethylthiophosphoric acid p-chlorophenyl ester;Stauffer R 1492;HSDB 1545;G-29288;EPA Pesticide Chemical Code 058101;BRN 2506804;UNII-X08H286BAN;AI3-25586;X08H286BAN;S-(((4-Chlorophenyl)thio)methyl) O,O-dimethylphosphorodithioate;Dimethyl p-chlorophenylthiomethyl dithiophosphate;Methyl Trithion (Technical Grade);Phosphorodithioic acid, S-(((4-chlorophenyl)thio)methyl) O,O-dimethyl ester;Methanethiol, ((p-chlorophenyl)thio)-, S-ester with O,O-dimethyl phosphorodithioate;NSC-231692;O,O-Dimethyl-S-(p-chlorophenylthiomethyl)phosphorodithioate;S-(((p-Chlorophenyl)thio)methyl) O,O-dimethyl phosphorodithioate;(4-chlorophenyl)sulfanylmethylsulfanyl-dimethoxy-sulfanylidene-lambda5-phosphane;Phosphorodithioic acid, S-(((p-chlorophenyl)thio)methyl) O,O-dimethyl ester;Phosphorodithioic acid, S-[[(4-chlorophenyl)thio]methyl] O,O-dimethyl ester;Carbophenothion-methyl 100 microg/mL in Acetonitrile;S-[[(p-Chlorophenyl)thio]methyl] O,O-dimethyl phosphorodithioate;Phosphorodithioic acid, S-[[(4-chlorophenyl)thio]methyl] O,O-dimethylester;Phosphorodithioic acid, S-[[(p-chlorophenyl)thio]methyl] O,O-dimethyl ester;Dimethyl (((p-chlorophenyl)thio)methyl) dithiophosphate;Dimethyl [[(p-chlorophenyl)thio]methyl] dithiophosphate;O,O-Dimethyl-S-(((p-chlorophenyl)thio)methyl)phosphorodithioate;O,O-Dimethyl-S-[[(p-chlorophenyl)thio]methyl]phosphorodithioate;(4-chlorophenyl)sulfanylmethylsulfanyl-dimethoxy-sulfanylidene-?^{5}-phosphane;C9H12ClO2PS3;METHYL TRITHION [HSDB];SCHEMBL5933780;DTXSID3040275;WLN: GR DS1SPS&O1&O1;NSC231692;Phosphorodithioic acid,O-dimethyl ester;1ST20534;LS-108068;Q27293162;Methanethiol, S-ester with O,O-dimethyl phosphorodithioate;S-(4-chlorophenylthio)methyl O,O-dimethyl phosphorodithioate;S-([(4-Chlorophenyl)sulfanyl]methyl) O,O-dimethyl dithiophosphate #

Chemical Property of Methyl trithion

Chemical Property:

• Vapor Pressure: 2.35E-05mmHg at 25°C
• Melting Point: -17.9°C
• Boiling Point: 370.5°Cat760mmHg
• Flash Point: 177.9°C
• PSA: 110.96000
• Density: 1.39g/cm³
• LogP: 5.29070
• Water Solubility.: 1.63mg/L(20 oC)
• XLogP3: 4.8
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 5
• Rotatable Bond Count: 6
• Exact Mass: 313.9425578
• Heavy Atom Count: 16
• Complexity: 239

Purity/Quality:

99.9% ^*data from raw suppliers

MethylTrithion(TechnicalGrade) ^*data from reagent suppliers

Safty Information:

• Hazard Codes: T,N
• Statements: 24/25-50/53
• Safety Statements: 28-36/37-45-60-61

MSDS Files:

SDS file from LookChem

Useful:

• Chemical Classes: Pesticides -> Organophosphate Insecticides
• Canonical SMILES: COP(=S)(OC)SCSC1=CC=C(C=C1)Cl

Technology Process of Methyl trithion

There total 3 articles about Methyl trithion which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

chloromethyl 4-chlorophenyl sulfide (7205-90-5) → Methyl Trithion (953-17-3)

Guidance literature:

With acetone;

Reference yield:

p-Chlorothiophenol (106-54-7) → Methyl Trithion (953-17-3)

Guidance literature:

Multi-step reaction with 2 steps

1: aqueous hydrochloric acid; aqueous formaldehyde-solution; hydrogen chloride

2: acetone

With hydrogenchloride; formaldehyd; acetone;

Reference yield:

→ Methyl Trithion (953-17-3)

Guidance literature:

upstream raw materials:

chloromethyl 4-chlorophenyl sulfide

p-Chlorothiophenol

Refernces