Technology Process of (1R,3aR,4S,7aR)-4-benzenesulfonyl-7a-methyl-1-<(1R,4S)-1,4,5-trimethyl-hexyl>-octahydroindene
There total 11 articles about (1R,3aR,4S,7aR)-4-benzenesulfonyl-7a-methyl-1-<(1R,4S)-1,4,5-trimethyl-hexyl>-octahydroindene which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
Multi-step reaction with 8 steps
1: KMnO4
3: 1.) Pb(OAc)4, pyridine, 2.) NaBH4, CeCl3*7H2O / 1.) CH2Cl2, 0 deg C, 10 min, 2.) CH3OH, 0 deg C, 3 h
4: 1.80 g / H2 / Pd/C / methanol / 16 h
5: Jones reagent / acetone
6: BF3*2H2O / CH2Cl2 / 16 h / 0 °C
7: 1.51 g / m-CPBA / CH2Cl2 / 3 h / 0 °C
8: 66 percent / LiAlH4 / tetrahydrofuran / 0.33 h / Heating
With
pyridine; lead(IV) acetate; sodium tetrahydroborate; potassium permanganate; lithium aluminium tetrahydride; jones reagent; cerium(III) chloride; boron trifluoride; hydrogen; 3-chloro-benzenecarboperoxoic acid;
palladium on activated charcoal;
In
tetrahydrofuran; methanol; dichloromethane; acetone;
- Guidance literature:
-
Multi-step reaction with 5 steps
1: 1.80 g / H2 / Pd/C / methanol / 16 h
2: Jones reagent / acetone
3: BF3*2H2O / CH2Cl2 / 16 h / 0 °C
4: 1.51 g / m-CPBA / CH2Cl2 / 3 h / 0 °C
5: 66 percent / LiAlH4 / tetrahydrofuran / 0.33 h / Heating
With
lithium aluminium tetrahydride; jones reagent; boron trifluoride; hydrogen; 3-chloro-benzenecarboperoxoic acid;
palladium on activated charcoal;
In
tetrahydrofuran; methanol; dichloromethane; acetone;
- Guidance literature:
-
Multi-step reaction with 7 steps
2: 1.) Pb(OAc)4, pyridine, 2.) NaBH4, CeCl3*7H2O / 1.) CH2Cl2, 0 deg C, 10 min, 2.) CH3OH, 0 deg C, 3 h
3: 1.80 g / H2 / Pd/C / methanol / 16 h
4: Jones reagent / acetone
5: BF3*2H2O / CH2Cl2 / 16 h / 0 °C
6: 1.51 g / m-CPBA / CH2Cl2 / 3 h / 0 °C
7: 66 percent / LiAlH4 / tetrahydrofuran / 0.33 h / Heating
With
pyridine; lead(IV) acetate; sodium tetrahydroborate; lithium aluminium tetrahydride; jones reagent; cerium(III) chloride; boron trifluoride; hydrogen; 3-chloro-benzenecarboperoxoic acid;
palladium on activated charcoal;
In
tetrahydrofuran; methanol; dichloromethane; acetone;
