1,1'-Dibenzyl-4,4'-bipyridinium dichloride

Base Information

• Chemical Name: 1,1'-Dibenzyl-4,4'-bipyridinium dichloride
• CAS No.: 1102-19-8
• Molecular Formula: C24H22Cl2N2
• Molecular Weight: 411.374
• Hs Code.: 29333990
• European Community (EC) Number: 214-158-5
• UNII: YTM57QC5KG
• Mol file: 1102-19-8.mol

Synonyms:1102-19-8;1,1'-Dibenzyl-4,4'-bipyridinium dichloride;1,1'-Dibenzyl-[4,4'-bipyridine]-1,1'-diium chloride;Benzyl viologen dichloride;Benzylviologen chloride;N,N'-Dibenzyl-gamma,gamma'-dipyridylium dichloride;4,4'-Bipyridinium, 1,1'-bis(phenylmethyl)-, dichloride;EINECS 214-158-5;NSC 409418;4,4'-BIPYRIDINIUM, 1,1'-DIBENZYL-, DICHLORIDE;1-benzyl-4-(1-benzylpyridin-1-ium-4-yl)pyridin-1-ium dichloride;1-benzyl-4-(1-benzylpyridin-1-ium-4-yl)pyridin-1-ium;dichloride;1,1'-Bis(phenylmethyl)-4,4'-bipyridinium dichloride;NSC-409418;1,1-DIBENZYL-4,4-BIPYRIDINIUM DICHLORIDE;C24H22N2.2Cl;Benzylviologen dichloride;Dibenzylviologen dichloride;YTM57QC5KG;C24H22Cl2N2;SCHEMBL1930045;Benzyl viologen dichloride, 97%;C24-H22-N2.2Cl;MFCD00011991;AKOS024370927;AS-64431;LS-44640;n,n'-dibenzyl-4,4'-bipyridinium dichloride;C(c1ccccc1)n2ccc(cc2)c3ccn(cc3)Cc4ccccc4;CS-0156500;D2137;FT-0633329;F18656;A802169;J-002401;1,1'-dibenzyl-4,4'-bipyridine-1,1'-diium chloride;1,1'-Dibenzyl-4,4'-bipyridinium Dichloride, Hydrate;1,1'-Dibenzyl-[4,4'-bipyridine]-1,1'-diiumchloride;1,1'-dibenzyl-[4,4'-bipyridine]-1,1'-diium dichloride;4,4'-Bipyridinium, 1,1'-bis(phenylmethyl)-, chloride (1:2)

Chemical Property of 1,1'-Dibenzyl-4,4'-bipyridinium dichloride

Chemical Property:

• Melting Point: 260
• PSA: 7.76000
• LogP: -1.96680
• Storage Temp.: Sealed in dry,Room Temperature
• Water Solubility.: Soluble in water
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 5
• Exact Mass: 408.1160041
• Heavy Atom Count: 28
• Complexity: 343

Purity/Quality:

98%,99%, ^*data from raw suppliers

1,1''-Dibenzyl-4,4''-bipyridiniumdichloride ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xn
• Hazard Codes: Xn
• Statements: 20/21/22-36/37/38
• Safety Statements: 26-36

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: C1=CC=C(C=C1)C[N+]2=CC=C(C=C2)C3=CC=[N+](C=C3)CC4=CC=CC=C4.[Cl-].[Cl-]
• Uses: BVD can be reduced to its neutral state by using sodium borohydride, which forms an n-type dopant for organic semiconductor based applications. It may be introduced to form a path for the transport of electrons from the thylakoid membranes to the mediator, which can be used in the fabrication of photo-driven bioanode. It also acts as a dopant with 2D layered materials to form an n-type chemical dopant that can be used to enhance the electrical properties of the triboelectric devices.

Technology Process of 1,1'-Dibenzyl-4,4'-bipyridinium dichloride

There total 4 articles about 1,1'-Dibenzyl-4,4'-bipyridinium dichloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 64.0%

4,4'-bipyridine (553-26-4) + benzyl chloride (100-44-7) → N,N'-dibenzylviologen dichloride (1102-19-8)

Guidance literature:

In ethanol; 1.) reflux, 4 h, 2.) RT, 2 d;

DOI:10.1021/j150668a041

Reference yield:

C24H22N2(1+)*Cl*Cl(1-) → N,N'-dibenzylviologen dichloride (1102-19-8)

Guidance literature:

In acetonitrile; at 15 ℃; Further Variations:; Pressures; Solvents; Temperatures; Kinetics;

DOI:10.1246/cl.2004.1542

Reference yield:

N,N'-dibenzylviologen dichloride (1102-19-8) → 1,1'-Dibenzyl-1λ5,1'λ5-[4,4']bi[pyridinyl]; compound with chlorine (1102-19-8)

Guidance literature:

With poly(N-vinyl pyrrolidine) matrix; In water; Mechanism; Irradiation; further polymer matrices;

DOI:10.1246/cl.1980.1145

upstream raw materials:

4,4'-bipyridine

benzyl chloride

Downstream raw materials:

benzyl vilogen cation radical

1,1'-dibenzyl-4,4'-bipyridinium

[1,1'-dibenzyl-4,4'-bipyridinium][Pt(maleonitriledithiolate)2]

[1,1'-dibenzyl-4,4'-bipyridinium][Cu(maleonitriledithiolate)2]

Refernces

• 1、 Osada, Yoshihito,Iriyama, Yu. "Plasma-Exposed Reduction of Solid and Solvated Viologens". . p. 2925 - 2926. Retrieved 1982.
• 2、 Li,Wang,Persaud,Mallouk. "ELECTROCHEMISTRY OF METALLOPORPHYRINS AND VIOLOGENS AT ZEOLITE Y MODIFIED ELECTRODES: EVIDENCE FOR ELECTRON TRAPPING BY MONOMOLECULAR PORPHYRIN LAYERS.". . p. 2592 - 2597. Retrieved 1988.