1-phenylmethoxydodecane

Base Information

• Chemical Name: 1-phenylmethoxydodecane
• CAS No.: 39695-18-6
• Molecular Formula: C19H32 O
• Molecular Weight: 276.462
• Mol file: 39695-18-6.mol

Synonyms:Ether,benzyl dodecyl (6CI); Benzyl dodecyl ether; NSC 71651

Chemical Property of 1-phenylmethoxydodecane

Chemical Property:

• Vapor Pressure: 5.77E-05mmHg at 25°C
• Boiling Point: 357°Cat760mmHg
• Flash Point: 184.2°C
• PSA: 9.23000
• Density: 0.891g/cm³
• LogP: 6.12410

Purity/Quality:

99%min ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1-phenylmethoxydodecane

There total 9 articles about 1-phenylmethoxydodecane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

Dodecanal (112-54-9) + benzyl alcohol (100-51-6,185532-71-2) → ((dodecyloxy)methyl)benzene (39695-18-6)

Guidance literature:

With phenyltellurotrimethylsilane; zinc(II) iodide; In benzene; for 3h; Ambient temperature;

DOI:10.1246/cl.1987.1331

Reference yield: 93.0%

1-dodecyl alcohol (112-53-8) + benzyl alcohol (100-51-6,185532-71-2) → dilauryl ether (4542-57-8) + dibenzyl ether (103-50-4) + ((dodecyloxy)methyl)benzene (39695-18-6)

Guidance literature:

With Cp*Ir(Cl)₂(nBu₂Im); silver trifluoromethanesulfonate; at 130 ℃; for 3h;

DOI:10.1002/chem.200801580

Reference yield: 92.0%

benzyl-(12-bromododecyl)-ether (95301-49-8) → ((dodecyloxy)methyl)benzene (39695-18-6)

Guidance literature:

With bis(p-methoxyphenyl)methanone; tetra-(n-butyl)ammonium iodide; potassium hydrogencarbonate; 4,4'-di-tert-butyl-2,2'-bipyridine; at 20 ℃; Irradiation;

DOI:10.1021/acscatal.1c05329

upstream raw materials:

1-dodecyl alcohol

benzyl chloride

Dodecanal

benzyl alcohol

Downstream raw materials:

lauryl acetate

dodecyl bromoacetate

(dodecyloxy)dimethyl(phenyl)silane

(dodecyloxy)(methyl)diphenylsilane

Refernces

• 1、 Agbossou-Niedercorn, Francine,Dixit, Ruchi,Merle, Nicolas,Michon, Christophe,Rysak, Vincent,Trivelli, Xavier,Vanka, Kumar. "Catalytic reductive deoxygenation of esters to ethers driven by hydrosilane activation through non-covalent interactions with a fluorinated borate salt". . p. 4586 - 4592. Retrieved 2020/08/14.
• 2、 Lu, Ping,Hou, Tianyuan,Gu, Xiangyong,Li, Pixu. "Visible-light-promoted conversion of alkyl benzyl ether to alkyl ester or alcohol via O-α-sp3 C-H cleavage". supporting information. p. 1954 - 1957. Retrieved 2015/04/27.