Phosphoric acid, phenyl bis(trimethylsilyl) ester

Base Information

• Chemical Name: Phosphoric acid, phenyl bis(trimethylsilyl) ester
• CAS No.: 10497-06-0
• Molecular Formula: C₁₂H₂₃O₄PSi₂
• Molecular Weight: 318.457
• DSSTox Substance ID: DTXSID501233388
• Mol file: 10497-06-0.mol

Synonyms:Phosphoric acid, phenyl bis(trimethylsilyl) ester;SCHEMBL5482457;DTXSID501233388;10497-06-0

Chemical Property of Phosphoric acid, phenyl bis(trimethylsilyl) ester

Chemical Property:

• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 6
• Exact Mass: 318.08724928
• Heavy Atom Count: 19
• Complexity: 310

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: C[Si](C)(C)OP(=O)(OC1=CC=CC=C1)O[Si](C)(C)C

Technology Process of Phosphoric acid, phenyl bis(trimethylsilyl) ester

There total 4 articles about Phosphoric acid, phenyl bis(trimethylsilyl) ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

dimethyl phenyl phosphate (10113-28-7) + phenylthiotrimethylsilane (4551-15-9) → Bis(trimethylsilyl)phenylphosphat (10497-06-0)

Guidance literature:

With perhydrodibenzo-18-crown-6; potassium thiophenolate; In benzene;

DOI:10.1016/S0040-4039(01)86110-4

Reference yield:

phosphoric acid phenyl ester-dipropyl ester (38299-59-1) + phenylthiotrimethylsilane (4551-15-9) → Bis(trimethylsilyl)phenylphosphat (10497-06-0)

Guidance literature:

With perhydrodibenzo-18-crown-6; potassium thiophenolate; In benzene;

DOI:10.1016/S0040-4039(01)86110-4

Reference yield:

O,O-diethyl O-phenyl phosphate (2510-86-3) + phenylthiotrimethylsilane (4551-15-9) → Bis(trimethylsilyl)phenylphosphat (10497-06-0)

Guidance literature:

With perhydrodibenzo-18-crown-6; potassium thiophenolate; In benzene;

DOI:10.1016/S0040-4039(01)86110-4

upstream raw materials:

dimethyl phenyl phosphate

phenylthiotrimethylsilane

O,O-diethyl O-phenyl phosphate

phosphoric acid phenyl ester-dipropyl ester

Downstream raw materials:

phosphoric acid monophenyl ester

Refernces

• 1、 Blackburn, G. Michael,Ingleson, David. "The Dealkylation of Phosphate and Phosphonate Esters by Iodotrimethylsilane: A Mild and Selective Procedure". . p. 1150 - 1153. Retrieved 2007/10/02.