1,3-Bis(methoxymethyl)urea

Base Information

• Chemical Name: 1,3-Bis(methoxymethyl)urea
• CAS No.: 141-07-1
• Molecular Formula: C5H12 N2 O3
• Molecular Weight: 148.162
• European Community (EC) Number: 205-454-5
• NSC Number: 75061
• UNII: K754ST3V4N
• DSSTox Substance ID: DTXSID5040126
• Nikkaji Number: J184.431H
• Wikidata: Q27282040
• Mol file: 141-07-1.mol

Synonyms:1,3-BIS(METHOXYMETHYL)UREA;141-07-1;1,3-Dimethoxymethylurea;Bis(methoxymethyl)urea;Kaurit W;Dimethylolurea dimethyl ether;Dimethoxydimethylolurea;N,N'-Bis(methoxymethyl)urea;N,N'-Dimethoxymethylurea;N,N'-Dimethylolurea dimethyl ether;Urea, 1,3-bis(methoxymethyl)-;Urea, N,N'-bis(methoxymethyl)-;UNII-K754ST3V4N;K754ST3V4N;HSDB 5632;EINECS 205-454-5;NSC 75061;NSC-75061;Urea, N ,N '-bis(methoxymethyl)-;1,3-bis-methoxymethyl-urea;Bis-methoxymethyl urea;NCIOpen2_000693;Urea,3-bis(methoxymethyl)-;Urea,N'-bis(methoxymethyl)-;SCHEMBL1860919;DTXSID5040126;1,3-Bis(methoxymethyl)harnstoff;N,N'-DI(METHOXYMETHYL)UREA;NSC75061;MFCD01940532;AKOS006351288;1,3-DIMETHOXYMETHYLUREA [HSDB];FT-0694310;W-109501;Q27282040

Chemical Property of 1,3-Bis(methoxymethyl)urea

Chemical Property:

• Vapor Pressure: 0.00293mmHg at 25°C
• Boiling Point: 284.7°Cat760mmHg
• Flash Point: 126°C
• PSA: 59.59000
• Density: 1.069g/cm³
• LogP: 0.27520
• XLogP3: -0.7
• Hydrogen Bond Donor Count: 2
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 4
• Exact Mass: 148.08479225
• Heavy Atom Count: 10
• Complexity: 86.9

Purity/Quality:

99%, ^*data from raw suppliers

1,3-BIS(METHOXYMETHYL)UREA 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Chemical Classes: Nitrogen Compounds -> Urea Compounds
• Canonical SMILES: COCNC(=O)NCOC

Technology Process of 1,3-Bis(methoxymethyl)urea

There total 5 articles about 1,3-Bis(methoxymethyl)urea which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

formaldehyd (50-00-0,30525-89-4,61233-19-0) + bis-(N'-hydroxymethyl-ureidomethyl)-ether (1910-86-7) → 3,5-bis(methoxymethyl)perhydro-1,3,5-oxadiazin-4-one (7388-44-5) + N,N'-bis(methoxymethyl)urea (141-07-1)

Guidance literature:

beim Behandeln des Reaktionsprodukts mit Chlorwasserstoff enthaltendem Methanol;

DOI:10.1007/BF00899274

Reference yield:

methanol (67-56-1) + 1,3-bis(hydroxymethyl)urea (140-95-4) → N,N'-bis(methoxymethyl)urea (141-07-1)

Guidance literature:

With hydrogenchloride;

Reference yield:

methanol (67-56-1) + tris(hydroxymethyl)urea (13329-70-9) → N,N'-bis(methoxymethyl)urea (141-07-1) + tris(methoxymethyl)urea (13822-64-5)

Guidance literature:

With hydrogenchloride; at 0 - 5 ℃; for 0.166667h; Yield given;

DOI:10.1246/bcsj.62.1930

upstream raw materials:

methanol

1,3-bis(hydroxymethyl)urea

formaldehyd

urea

Downstream raw materials:

methanol

N-methoxymethyl-N'-hydroxymethylurea

formaldehyd

N,N'-bis-butoxymethyl-urea

Refernces

• 1、 Shiba, Ryuichi,Takahashi, Miyuki,Ebisuno, Toichi,Takimoto, Michiaki. "The Formation Pathway of 3,5-Bis(methoxymethyl)perhydro-1,3,5-oxadiazin-4-one". . p. 1930 - 1933. Retrieved 2007/10/02.