Phosphine, dibutylphenyl-

Base Information

• Chemical Name: Phosphine, dibutylphenyl-
• CAS No.: 6372-44-7
• Molecular Formula: C14H23 P
• Molecular Weight: 222.31
• Hs Code.: 2902909090
• DSSTox Substance ID: DTXSID70213145
• Nikkaji Number: J50.206E
• Wikidata: Q83088428
• Mol file: 6372-44-7.mol

Synonyms:Phosphine, dibutylphenyl-;dibutyl(phenyl)phosphane;6372-44-7;Dibutylphenylphosphine;di-n-Butylphenylphosphine;Dibutyl-fenylfosfin;Dibutyl-fenylfosfin [Czech];TL 464;BRN 0743952;4-16-00-00950 (Beilstein Handbook Reference);phenyldibutylphosphine;di-n-butylphenyl-phosphine;SCHEMBL49367;C14H23P;DTXSID70213145;C14-H23-P;MFCD00015253;LS-105958;BB 0221072

Chemical Property of Phosphine, dibutylphenyl-

Chemical Property:

• Vapor Pressure: 0.00143mmHg at 25°C
• Boiling Point: 306.1°C at 760 mmHg
• Flash Point: 144.9°C
• PSA: 13.59000
• LogP: 4.39400
• XLogP3: 4
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 7
• Exact Mass: 222.153737731
• Heavy Atom Count: 15
• Complexity: 130

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Statements: 20/21/22
• Safety Statements: 26-36/37/39

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCCCP(CCCC)C1=CC=CC=C1

Technology Process of Phosphine, dibutylphenyl-

There total 27 articles about Phosphine, dibutylphenyl- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

dibutyl phenyl phosphate (10557-66-1) → (dibutyl)(phenyl)phosphine (6372-44-7)

Guidance literature:

With 1,1,3,3-Tetramethyldisiloxane; In neat (no solvent); at 175 ℃; for 7h; Reagent/catalyst; Temperature; Time; Inert atmosphere; Microwave irradiation; Green chemistry;

DOI:10.1002/hc.21376

Reference yield: 90.0%

n-butyl magnesium bromide (693-03-8) + cis-2,10-dimethyl-<1,2,3>benzothiadiphospholo<2,3-b><1,2,3>benzothiadiphosphole (119841-34-8,127780-84-1) + phenylmagnesium bromide → (dibutyl)(phenyl)phosphine (6372-44-7) + 4-methyl-2-[(5-methyl-2-sulfanylphenyl)phosphanyl]benzenethiol (736137-64-7)

Guidance literature:

n-butyl magnesium bromide; cis-2,10-dimethyl-<1,2,3>benzothiadiphospholo<2,3-b><1,2,3>benzothiadiphosphole; In tetrahydrofuran; for 0.0833333h;

phenylmagnesium bromide; In tetrahydrofuran;

DOI:10.1021/jo0502145

Reference yield: 88.0%

fluorobenzene (462-06-6) + sodium dibutylphosphide (51526-34-2) → (dibutyl)(phenyl)phosphine (6372-44-7)

Guidance literature:

With 15-crown-5; In tetrahydrofuran; at 25 ℃; for 1h; Inert atmosphere;

DOI:10.1021/acs.organomet.0c00295

upstream raw materials:

Dichlorophenylphosphine

n-butyl magnesium bromide

Phenyl-trichlor-phosphoniumchlorid

n-Butyl chloride

Downstream raw materials:

dibutyl-methyl-phenyl-phosphonium; iodide

di-n-butylphosphine

butyl(phenyl)phosphine

Dimethyl(phenyl)phosphine

Refernces

• 1、 Kovács, Tamara,Urbanics, Anita,Csatlós, Flóra,Keglevich, Gy?rgy. "A study on the deoxygenation of trialkyl-, dialkyl-phenyl- and alkyl-diphenyl phosphine oxides by hydrosilanes". . . Retrieved 2017/08/26.
• 2、 Owen, Jonathan S.,Chan, Emory M.,Liu, Haitao,Alivisatos, A. Paul. "Precursor conversion kinetics and the nucleation of cadmium selenide nanocrystals". experimental part. p. 18206 - 18213. Retrieved 2011/03/21.