Iron(III)Acetylacetonate

Base Information

• Chemical Name: Iron(III)Acetylacetonate
• CAS No.: 14024-18-1
• Molecular Formula: C15H21FeO6
• Molecular Weight: 353.175
• Hs Code.: 29420000
• European Community (EC) Number: 237-853-5
• Wikipedia: Tris(acetylacetonato)iron(III)
• Mol file: 14024-18-1.mol

Synonyms:Iron(III)Acetylacetonate;14024-18-1;SCHEMBL897914;NS00085359;Iron, tris(2,4-pentanedionato-.kappa.O,.kappa.O')-, (OC-6-11)-

Chemical Property of Iron(III)Acetylacetonate

Chemical Property:

• Appearance/Colour: dark red powder
• Vapor Pressure: 0.174mmHg at 25°C
• Melting Point: 180-182 °C (dec.)(lit.)
• Boiling Point: 110 °C 2 mm
• Flash Point: 43.1ºC
• PSA: 102.42000
• Density: 5.24 g/mL at 25 °C(lit.)
• LogP: 1.66100
• Storage Temp.: Store below +30°C.
• Solubility.: Soluble in toluene.
• Water Solubility.: 2 g/L (20 ºC)
• Hydrogen Bond Donor Count: 3
• Hydrogen Bond Acceptor Count: 6
• Rotatable Bond Count: 3
• Exact Mass: 356.092224
• Heavy Atom Count: 22
• Complexity: 380

Purity/Quality:

99% ^*data from raw suppliers

Iron(III) acetylacetonate ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xn
• Hazard Codes: Xn
• Statements: 22-36
• Safety Statements: 26-37/39

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Chemical Classes: Metals -> Organic Compounds, Metal Salts
• Canonical SMILES: CC(=CC(=O)C)O.CC(=CC(=O)C)O.CC(=CC(=O)C)O.[Fe]
• Uses: Moderating and combustion catalyst, solid fuel catalyst, bonding agent, curing accelerator, intermediate. Iron(III) 2,4-pentanedionate is used as a precatalyst and reagent in organic chemistry. It acts as a precursor for highly crystalline (Zn, Fe)Fe2O4 Chemical Synthesis of Monodisperse Magnetic Nanoparticles

Technology Process of Iron(III)Acetylacetonate

There total 22 articles about Iron(III)Acetylacetonate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

iron(III) chloride hexahydrate (121714-78-1,24290-40-2,58694-80-7,10025-77-1,64333-00-2) + potassium acetylacetonate (19393-11-4) → iron(III)-acetylacetonate (14024-18-1)

Guidance literature:

In ethanol; at pH 5-6 by the method of Fackler, Progress in Inorganic Chemistry, 1966, 7, 403; subliming twice (t=180 °C, P=5E-2 torr); elem. anal.;

Reference yield: 90.0%

iron(III) chloride (7705-08-0) + acetylacetone (123-54-6,81235-32-7) → iron(III)-acetylacetonate (14024-18-1)

Guidance literature:

With ammonia; In water; anhyd. FeCl3 dissolved in water, excess ammonia soln. added slowly withstirring and mixt heated on steam-bath for 15-20 min, Fe(OH)3 filtered off, washed with water and heated with acetylacetone on steam-bath for 35 min.; mixt. cooled, crystalsdried and recrystd. from ethanol; elem. anal.;

DOI:10.1039/DT9830000839

Reference yield: 80.0%

iron(III) chloride (7705-08-0) + sodium (Z)-4-oxopent-2-en-2-olate (1118-67-8) → iron(III)-acetylacetonate (14024-18-1)

Guidance literature:

In solid; byproducts: NaCl; mechanical treatment of the react. mixt. (FeCl3 (1.18 mmol) and an org.compd. (3.55 mmol)) in stainless steel reactors; the steel balls were used as an activating packing; in a dry box under N2; self-propagating synthesis; isolation by sublimation or extn.; elem. anal.; IR-spectroscopy; X-ray diffraction;

upstream raw materials:

acetylacetone

iron pentacarbonyl

iron(III) chloride hexahydrate

potassium acetylacetonate

Downstream raw materials:

iron pentacarbonyl

Fe₂(CO)8^(2-)

acetylacetone

[Fe(Fe(N(CH₂CH₂S)3)(CNCy))2-S,S']

Refernces

• 1、 Hedewy,Hoffmann. "ELECTRON PARAMAGNETIC RESONANCE OF FERRIC ACETYL ACETONATE.". . p. 129 - 133. Retrieved 1986.
• 2、 Devi, Meghali,Ganguly, Sreejeeb,Bhuyan, Bishal,Dhar, Siddhartha Sankar,Vadivel, Sethumathavan. "A Novel [Fe(acac)3] Interspersed g-C3N4 Heterostructure for Environmentally Benign Visible-Light-Driven Oxidation of Alcohols". . p. 4819 - 4825. Retrieved 2018.
• 3、 Vu?ini?-Vasi?,Antic,Kremenovi?,Nikolic,Blanusa,Raki?,Spasojevic,Kapor. "Investigation of nanocrystalline phases in Li-La-Fe-O system formed by the decomposition of acetylacetonato complexes". . p. 322 - 326. Retrieved 2007.
• 4、 Slizhov, Yu. G.,Matveeva,Minakova. "Effect of technique of applying layers of metal acetylacetonates on acid-base and chromatographic properties of sorbents". . p. 1376 - 1382. Retrieved 2013.
• 5、 Conradie,Conradie,Erasmus. "Immobilisation of iron tris(β-diketonates) on a two-dimensional flat amine functionalised silicon wafer: A catalytic study of the formation of urethane, from ethanol and a diisocyanate derivative". . p. 52 - 59. Retrieved 2014.
• 6、 Chaudhuri, Mihir K.,Ghosh, Soumitra K.. "Novel Synthesis of Tris(acetylacetonato)iron(III)". . p. 839 - 840. Retrieved 1983.
• 7、 Butler, Anthony R.,Calsy, Adrianne M.,Glidewell, Christopher. "The pentacyanonitrosylferrate(2-) ion. IV. Reactions with the carbanions of pentane-2,4-dione and 3-methylpentane-2,4-dione". . p. 439 - 446. Retrieved 1988.