1-trans-2-Ethylmethylcyclopentane

Base Information

• Chemical Name: 1-trans-2-Ethylmethylcyclopentane
• CAS No.: 930-90-5
• Molecular Formula: C8H16
• Molecular Weight: 112.215
• European Community (EC) Number: 213-227-7
• Nikkaji Number: J293.403E
• Mol file: 930-90-5.mol

Synonyms:trans-1-Ethyl-2-methylcyclopentane;1-trans-2-Ethylmethylcyclopentane;BSKOLJVTLRLTHE-YUMQZZPRSA-N;AKOS006273838

Chemical Property of 1-trans-2-Ethylmethylcyclopentane

Chemical Property:

• Vapor Pressure: 15.6mmHg at 25°C
• Melting Point: -105.9°C
• Refractive Index: 1.4195
• Boiling Point: 124.1°Cat760mmHg
• Flash Point: 13.5°C
• Density: 0.767g/cm³
• XLogP3: 3.8
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 1
• Exact Mass: 112.125200510
• Heavy Atom Count: 8
• Complexity: 66.4

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CCC1CCCC1C
• Isomeric SMILES: CC[C@H]1CCC[C@@H]1C

Technology Process of 1-trans-2-Ethylmethylcyclopentane

There total 26 articles about 1-trans-2-Ethylmethylcyclopentane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

octane (111-65-9) → 2-methylheptane (592-27-8) + 4-methylheptane (589-53-7) + 3-methylheptane (589-81-1) + o-xylene (95-47-6) + 2-ethyl-1-methylcyclopentane (930-89-2,930-90-5,3726-46-3) + n-propylcyclopentane (2040-96-2) + ethylbenzene (100-41-4,27536-89-6)

Guidance literature:

With 0.93 wt.% platinum on non-acidic silica; hydrogen; at 393 ℃; under 750.075 Torr; Autoclave;

DOI:10.1016/j.apcata.2012.03.010

Reference yield:

4-Ethylguaiacol (2785-89-9) → methanol (67-56-1) + 2-ethyl-1-methylcyclopentane (930-89-2,930-90-5,3726-46-3) + ethyl-cyclohexane (1678-91-7)

Guidance literature:

With phosphoric acid; 5% Pd(II)/C(eggshell); hydrogen; In water; at 249.84 ℃; for 0.5h; under 37503.8 Torr; Autoclave;

DOI:10.1016/j.jcat.2011.02.001

Reference yield:

6-iodohept-1-ene (13389-36-1) + methylmagnesium chloride (676-58-4) → 2-ethyl-1-methylcyclopentane (930-89-2,930-90-5,3726-46-3)

Guidance literature:

With C₃₂H₃₀ClN₂NiP; In tetrahydrofuran; N,N-dimethyl acetamide; at -20 ℃; for 2h; Inert atmosphere;

DOI:10.1021/ja200270k

upstream raw materials:

1-methyl-2-ethylcyclopentene

methyl 2-methylcyclopentyl ketone

2-ethyl-1-methyl-cyclopentanol

hydrogenchloride

Downstream raw materials:

1,1-dimethylcyclohexane

m-xylene

o-xylene

para-xylene

Refernces

• 1、 Haas, Andreas,Rabl, Sandra,Ferrari, Marco,Calemma, Vincenzo,Weitkamp, Jens. "Ring opening of decalin via hydrogenolysis on Ir/- and Pt/silica catalysts". experimental part. p. 97 - 109. Retrieved 2012/07/13.
• 2、 Ren, Peng,Vechorkin, Oleg,Von Allmen, Kim,Scopelliti, Rosario,Hu, Xile. "A structure-activity study of Ni-catalyzed alkyl-alkyl kumada coupling. Improved catalysts for coupling of secondary alkyl halides". supporting information; experimental part. p. 7084 - 7095. Retrieved 2011/06/26.