(η5-methylcyclopentadienyl)dicarbonyl(hydrido)(triphenylgermyl)manganese

Base Information

• Chemical Name: (η5-methylcyclopentadienyl)dicarbonyl(hydrido)(triphenylgermyl)manganese
• CAS No.: 90148-95-1
• Molecular Formula: C₂₆H₂₃GeMnO₂
• Molecular Weight: 494.995
• Mol file: 90148-95-1.mol

Synonyms:(η5-methylcyclopentadienyl)dicarbonyl(hydrido)(triphenylgermyl)manganese

Chemical Property of (η5-methylcyclopentadienyl)dicarbonyl(hydrido)(triphenylgermyl)manganese

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (η5-methylcyclopentadienyl)dicarbonyl(hydrido)(triphenylgermyl)manganese

There total 2 articles about (η5-methylcyclopentadienyl)dicarbonyl(hydrido)(triphenylgermyl)manganese which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 57.0%

tetraethylammonium (η5-methylcyclopentadienyl)dicarbonyl(triphenylgermyl)manganese (68168-06-9) → (η5-methylcyclopentadienyl)dicarbonyl(hydrido)(triphenylgermyl)manganese (90148-95-1)

Guidance literature:

With HCl; In tetrahydrofuran; The soln. of HCl in THF was added dropwise to a soln. of complex in THF (N2 atm.);; evapd., extd. with toluene, filtered, concd., hexane was added, standing at -20°C;;

Reference yield: 31.0%

methylcyclopentadienyl manganese(I) tricarbonyl + triphenylgermane (2816-43-5) → (η5-methylcyclopentadienyl)dicarbonyl(hydrido)(triphenylgermyl)manganese (90148-95-1)

Guidance literature:

In tetrahydrofuran; byproducts: CO; Irradiation (UV/VIS); A soln. of reagents in THF was irradiated overnight (N2 atm.);; evapd., dissolved in hexane, filtered, concd., crystd. at -20°C; elem. anal.;;

Reference yield: 90.0%

lithium aluminium tetrahydride (16853-85-3) + (η5-methylcyclopentadienyl)dicarbonyl(hydrido)(triphenylgermyl)manganese (90148-95-1) → triphenylgermane (2816-43-5)

Guidance literature:

With CCl₄; In benzene; CCl4, 48 h; reduced with LiAlH4 in Et2O at room temp.;;

upstream raw materials:

triphenylgermane

tetraethylammonium (η5-methylcyclopentadienyl)dicarbonyl(triphenylgermyl)manganese

Downstream raw materials:

tetraethylammonium (η5-methylcyclopentadienyl)dicarbonyl(triphenylgermyl)manganese

triphenylgermane

triphenylmethoxygermane

Refernces