(Acetylacetonate)dicarbonylrhodium

Base Information

• Chemical Name: (Acetylacetonate)dicarbonylrhodium
• CAS No.: 14874-82-9
• Molecular Formula: C7H7O4Rh
• Molecular Weight: 258.03
• Hs Code.: 28439000
• UNII: H77Y3D36FX
• Mol file: 14874-82-9.mol

Synonyms:Rh(acac)(CO)2;Acetylacetonatodicarbonylrhodium(I);Rh(CO)2(acac);H77Y3D36FX;(Acetylacetonate)dicarbonylrhodium;Rhodium biscarbonyl acetylacetonate;AKOS015901868;BP-30244;Rhodium, (2,4-pentanedionato)dicarbonyl-;(Acetylacetonato)dicarbonylrhodium(I) 39%Rh;(SP-4-2)-Dicarbonyl(2,4-pentanedionato-kappaO2,kappaO4)rhodium;Rhodium, dicarbonyl(2,4-pentanedionato-kappaO2,kappaO4)-, (SP-4-2)-

Chemical Property of (Acetylacetonate)dicarbonylrhodium

Chemical Property:

• Appearance/Colour: Red/green crystalline powder
• Vapor Pressure: 0.13Pa at 25℃
• Melting Point: 154-156 °C(lit.)
• PSA: 26.30000
• Density: 1.96[at 20℃]
• LogP: 0.54410
• Storage Temp.: Inert atmosphere,Room Temperature
• Solubility.: Soluble in acetone
• Water Solubility.: insoluble
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 1
• Exact Mass: 257.93993
• Heavy Atom Count: 12
• Complexity: 100

Purity/Quality:

99.9% ^*data from raw suppliers

(Acetylacetonato)dicarbonylrhodium(I) ^*data from reagent suppliers

Safty Information:

• Pictogram(s): Xi
• Hazard Codes: Xi,F,T
• Statements: 36/37/38-44-43-25
• Safety Statements: 26-37/39-45-36/37/39-24/25

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Canonical SMILES: CC(=CC(=O)C)[O-].[C-]#[O+].[C-]#[O+].[Rh]
• Isomeric SMILES: C/C(=C/C(=O)C)/[O-].[C-]#[O+].[C-]#[O+].[Rh]
• Uses: (Acetylacetonato)dicarbonylrhodium(I) is used in in situ formation of a floors-soluble hydroformylation catalyst of interest in molecular engineering. It is also used as a catalyst for various carbonylation reactions, silylcarbocyclizations, conjugate additions to eons, carbamoylstannation, and reduction of aromatic nitro compounds. It is also used in Hydroformylation reaction. Employed in in situ formation of a fluorous-soluble hydroformylation catalyst of interest in molecular engineering. Umicore Precatalysts for Asymmetric and Cross-Coupling CatalysisCatalyst for various carbonylation reactions, silylcarbocyclizations,conjugate additions to enones, carbamoylstannation,and reduction of aromatic nitro compounds