2-chlorotetradecane

Base Information

• Chemical Name: 2-chlorotetradecane
• CAS No.: 51191-27-6
• Molecular Formula: C14H29Cl
• Molecular Weight: 232.8331
• Mol file: 51191-27-6.mol

Synonyms:

Chemical Property of 2-chlorotetradecane

Chemical Property:

• Vapor Pressure: 0.00315mmHg at 25°C
• Boiling Point: 292.8°C at 760 mmHg
• Flash Point: 120.2°C
• Density: 0.857g/cm³

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 2-chlorotetradecane

There total 4 articles about 2-chlorotetradecane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

1-tetradecene (1120-36-1) → 2-chlorotetradecane (34942-43-3,51191-27-6)

Guidance literature:

With hydrogenchloride; silica gel; In water; at 0 - 20 ℃; for 18h;

DOI:10.1016/j.tetlet.2018.10.043

Reference yield:

C20H34Cl2Te (83486-01-5) → diphenyl ditelluride (32294-60-3) + 2-chlorotetradecane (34942-43-3,51191-27-6)

Guidance literature:

With sodium chloride; In N,N-dimethyl-formamide; at 100 ℃; Yield given;

DOI:10.1246/cl.1982.1081

Reference yield:

tetradecan-1-yl phenyl telluride (77953-90-3) → 2-chlorotetradecane (34942-43-3,51191-27-6)

Guidance literature:

Multi-step reaction with 2 steps

1: sulfuryl chloride / CCl₄ / Ambient temperature

2: sodium chloride / dimethylformamide / 100 °C

With sulfuryl dichloride; sodium chloride; In tetrachloromethane; N,N-dimethyl-formamide;

DOI:10.1246/cl.1982.1081

upstream raw materials:

tetradecan-2-ol

C₂₀H₃₄Cl₂Te

tetradecan-1-yl phenyl telluride

1-tetradecene

Downstream raw materials:

tetradecane

4-(1-Methyl-tridecyloxy)-benzoic acid

Refernces

• 1、 Chikamatsu, Kiyofumi,Otsubo, Tetsuo,Ogura, Fumio,Yamaguchi, Hachiro. "PREPARATION OF ALKYL HALIDES VIA ORGANOTELLURIUMS". . p. 1081 - 1084. Retrieved 2007/10/02.