Bendiocarb

Base Information

• Chemical Name: Bendiocarb
• CAS No.: 22781-23-3
• Molecular Formula: C11H13NO4
• Molecular Weight: 223.229
• Hs Code.: 29329990
• European Community (EC) Number: 245-216-8
• UN Number: 2757
• UNII: QFH0ZU0A5U
• DSSTox Substance ID: DTXSID9032327
• Nikkaji Number: J3.469J
• Wikipedia: Bendiocarb
• Wikidata: Q417017
• NCI Thesaurus Code: C163589
• Metabolomics Workbench ID: 54989
• ChEMBL ID: CHEMBL465018
• Mol file: 22781-23-3.mol

Synonyms:bendiocarb;FICAM;FICAM 80W;FICAM W

Chemical Property of Bendiocarb

Chemical Property:

• Vapor Pressure: 0.00124mmHg at 25°C
• Melting Point: 128-130oC
• Refractive Index: 1.523
• Boiling Point: 298.769 °C at 760 mmHg
• PKA: 11.98±0.46(Predicted)
• Flash Point: 134.491 °C
• PSA: 56.79000
• Density: 1.204 g/cm³
• LogP: 2.30300
• Storage Temp.: 0-6°C
• Water Solubility.: 280 mg l-1 (20 °C)
• XLogP3: 1.7
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 2
• Exact Mass: 223.08445790
• Heavy Atom Count: 16
• Complexity: 279
• Transport DOT Label: Poison

Purity/Quality:

Bendiocarb ^*data from reagent suppliers

Safty Information:

• Pictogram(s): T,N
• Hazard Codes: T,N
• Statements: 21-23/25-50/53
• Safety Statements: 22-36/37-45-60-61

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Chemical Classes: Pesticides -> Carbamate Insecticides
• Canonical SMILES: CC1(OC2=C(O1)C(=CC=C2)OC(=O)NC)C
• Description: Bendiocarb belongs to a kind of carbamate insecticide. It can be used in homes, industrial plants and food storage sites for the treatment of various kinds of insects including mosquitoes, flies, wasps, ants, fleas, cockroaches, spider, silverfish, ticks and other pests in homes, industrial plants, and food storage sites. In agriculture, it is used for the treatment of a variety of insects such as beetles, aphids, mites and caterpillars. Bendiocarb can block the activity of some enzymes necessary for the normal nerve transmission, further affecting the normal operation of the insects’ nervous system. It can kill the pests through either contact or ingestion. However, its applications have been cancelled in some countries including the United States due to its toxicity effects on Human beings and other animals including birds and fishes. Bendiocarb is an odourless, non-corrosive white crystalline solid. Bendiocarb is a carbamate ester. Carbamates are chemically similar to but more reactive than amides. Like amides, they form polymers such as polyurethane resins. Some of the formulations of bendiocarb are classified as general use pesticides (GUP), while Turcam and its 2.5 G formulation have been classified as restricted use pesticides (RUP). Bendiocarb is stable under normal temperatures and pressures, but should not be mixed with alkaline preparations. Thermal decomposition products may include toxic oxides of nitrogen. It is noncorrosive. Flammable gaseous hydrogen is produced by the combination of active metals or nitrides with carbamates. Strongly oxidising acids, peroxides, and hydroperoxides are incompatible with carbamates. Bendiocarb as a carbamate insecticide is effective against a wide range of insects that cause nuisance and act as disease vectors. It is used to control mosquitoes, flies, wasps, ants, fleas, cockroaches, silverfish, ticks, and other pests in homes, industrial plants, and food storage sites. Bendiocarb is also used as a seed treatment on sugar beets and maize and against snails and slugs. Pesticides containing bendiocarb are formulated as dusts, granules, ultra-low volume sprays, and wettable powders. It gets hydrolysed rapidly in alkali media and slows under acid and neutral conditions. Flammable gaseous hydrogen is produced by the combination of active metals or nitrides with carbamates.
• Uses: Contact insecticide used to control beetles, wireworms, flies, wasps and mosquitoes in beets and maize. Bendiocarb is a benzodioxolyl carbamate derivative. Bendiocarb is commonly used as an insecticide in agriculture against a wide range of pests and insects. Bendiocarb is one of the insecticides recomm ended by world health organization (WHO) for use in malaria control. Contact insecticide. Bendiocarb is a contact and ingested insecticide with some systemic activity in crop plants. It is active against many public health, industrial and storage pests such as Formicidae, Blattodae, Culicidae, Muscidae and Siphonaptera.

Technology Process of Bendiocarb

There total 2 articles about Bendiocarb which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.2%

2,2-Dimethyl-4-hydroxy-1,3-benzodioxole (22961-82-6) + methyl isocyanate (624-83-9) → bendiocarb (22781-23-3)

Guidance literature:

With triethylamine; In 5,5-dimethyl-1,3-cyclohexadiene; at 60 ℃; for 2h; Temperature; Solvent;

Reference yield: 91.0%

→ bendiocarb (22781-23-3)

Guidance literature:

Reference yield: 58.0%

bendiocarb (22781-23-3) + 1,3-benzodioxol-4-yl N-acetyl-N-methylcarbamate (40373-39-5) → 2,2-dimethyl-1,3-benzodioxol-4-yl N-acetyl-N-methylcarbamate (22791-33-9)

Guidance literature:

In acetic anhydride;

upstream raw materials:

2,2-Dimethyl-4-hydroxy-1,3-benzodioxole

methyl isocyanate

Downstream raw materials:

2,2-Dimethyl-4-hydroxy-1,3-benzodioxole

2,2-dimethyl-1,3-benzodioxol-4-yl N-propionyl-N-methylcarbamate

2,2-dimethyl-1,3-benzodioxol-4-yl N-acetyl-N-methylcarbamate

Refernces

• 1、 -. "SYSTEM FOR PROTECTING GOODS DURING TRANSPORT". . . Retrieved 2013/02/28.
• 2、 -. "Arthropodicidal granular formulation". . . Retrieved 2008/06/13.