[2,6-(ⁱPr₂PO)₂C₆H₃]NiCl

Base Information

• Chemical Name: [2,6-(ⁱPr₂PO)₂C₆H₃]NiCl
• CAS No.: 948311-76-0
• Molecular Formula: C₁₈H₃₁ClNiO₂P₂
• Molecular Weight: 435.533
• Mol file: 948311-76-0.mol

Synonyms:[2,6-(ⁱPr₂PO)₂C₆H₃]NiCl

Chemical Property of [2,6-(ⁱPr₂PO)₂C₆H₃]NiCl

Chemical Property:

Purity/Quality:

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MSDS Files:

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Technology Process of [2,6-(ⁱPr₂PO)₂C₆H₃]NiCl

There total 2 articles about [2,6-(ⁱPr₂PO)₂C₆H₃]NiCl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

C28H39N2NiO2P2(1+)*Cl(1-) → [2,2]bipyridinyl (366-18-7) + [2,6-(iPr2PO)2C6H3]NiCl (948311-76-0)

Guidance literature:

In acetonitrile; Equilibrium constant;

DOI:10.1039/d1nj01355f

Reference yield:

C30H39N2NiO2P2(1+)*Cl(1-) → 1,10-Phenanthroline (66-71-7) + [2,6-(iPr2PO)2C6H3]NiCl (948311-76-0)

Guidance literature:

In acetonitrile; Equilibrium constant;

DOI:10.1039/d1nj01355f

Reference yield: 92.0%

[2,6-(iPr2PO)2C6H3]NiCl (948311-76-0) + silver benzoate (532-31-0) → C25H36NiO4P2

Guidance literature:

In tetrahydrofuran; at 20 ℃; for 6h; Inert atmosphere; Schlenk technique; Darkness;

DOI:10.1021/acs.organomet.8b00888

Downstream raw materials:

[2,6-((i)PrPO)2C₆H₃]NiOCH₂Ph

[(2,6-((i-Pr)2PO)2C₆H₃)Ni(SC₆H₄-p-CF₃)]

[(2,6-((i-Pr)2PO)2C₆H₃)Ni(SC₆H₅)]

[(2,6-((i-Pr)2PO)2C₆H₃)Ni(SC₆H₄-p-Me)]

Refernces