10,10-Oxybisphenoxarsine

Base Information

• Chemical Name: 10,10-Oxybisphenoxarsine
• CAS No.: 58-36-6
• Deprecated CAS: 107391-69-5,53923-27-6,64684-28-2,64887-10-1,115728-29-5,1463955-27-2,115728-29-5,53923-27-6,64684-28-2,64887-10-1
• Molecular Formula: C24H16As2O3
• Molecular Weight: 502.232
• European Community (EC) Number: 200-377-3
• UN Number: 1760,1557
• UNII: 1R0GEE9L5Z
• DSSTox Substance ID: DTXSID0032443
• Nikkaji Number: J9.323H
• Wikidata: Q3376217
• Mol file: 58-36-6.mol

Synonyms:Phenoxarsine,10,10'-oxydi- (6CI,7CI,8CI);10,10'-Bis(phenoxarsinyl) oxide;10,10'-Oxidiphenoxarsine;10,10'-Oxybisphenoxarsine;Bis(10-phenoxarsyl) oxide;Bis(phenoxarsin-10-yl) ether;10H-Phenoxarsine, 10,10'-oxybis-;SA 546;Vinadine;Vinyzene(pesticide);Vinyzene BP 5;Vinyzene BP 5-2DIDP;Vinyzene BP505;Vinyzene SB 1PR;

Chemical Property of 10,10-Oxybisphenoxarsine

Chemical Property:

• Appearance/Colour: clear light yellow liquid with a mild odor
• Vapor Pressure: 7.77E-11mmHg at 25°C
• Melting Point: 180-184 °C
• Boiling Point: 531.3 °C at 760 mmHg
• Flash Point: 214.1 °C
• PSA: 27.69000
• Density: 1.40-1.42
• LogP: 2.82620
• Storage Temp.: Sealed in dry,Room Temperature
• Water Solubility.: insoluble
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 3
• Rotatable Bond Count: 2
• Exact Mass: 501.95313
• Heavy Atom Count: 29
• Complexity: 482
• Transport DOT Label: Corrosive

Purity/Quality:

99% ^*data from raw suppliers

10,10'-Oxybis(phenoxarsine) 95+% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

• Chemical Classes: Metals -> Arsenic Compounds, Organic
• Canonical SMILES: C1=CC=C2C(=C1)OC3=CC=CC=C3[As]2O[As]4C5=CC=CC=C5OC6=CC=CC=C64

Technology Process of 10,10-Oxybisphenoxarsine

There total 8 articles about 10,10-Oxybisphenoxarsine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.8%

10-<2-chloro-1-(chloromethyl)ethoxy>phenoxarsine → 1,3-Dichloro-2-propanol (96-23-1) + 10,10,oxybisphenoxarsine (58-36-6)

Guidance literature:

With water; In acetone;

Reference yield:

→ 10,10,oxybisphenoxarsine (58-36-6)

Guidance literature:

With ethanol; ammonia;

Reference yield:

10-chloro-10H-phenoxarsine (2865-70-5) → 10,10,oxybisphenoxarsine (58-36-6)

Guidance literature:

Multi-step reaction with 2 steps

1: toluene; diethyl ether

2: O₂

With oxygen; In diethyl ether; toluene;

upstream raw materials:

10-sec-butyl-10H-phenoxarsine

diphenylether

10-allylphenoxarsine

10-tert-butylphenoxarsine

Downstream raw materials:

10-iodophenoxarsine

10-oxo-10H-10λ⁵-phenoxarsin-10-ol

Refernces