CH(O)C₆H₂(CH₃)(CO)ORh(P(C₆H₅)3)2NO₂

Base Information

• Chemical Name: CH(O)C₆H₂(CH₃)(CO)ORh(P(C₆H₅)3)2NO₂
• CAS No.: 222532-71-0
• Molecular Formula: C₄₅H₃₆NO₅P₂Rh
• Molecular Weight: 835.638
• Mol file: 222532-71-0.mol

Synonyms:CH(O)C₆H₂(CH₃)(CO)ORh(P(C₆H₅)3)2NO₂

Chemical Property of CH(O)C₆H₂(CH₃)(CO)ORh(P(C₆H₅)3)2NO₂

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of CH(O)C₆H₂(CH₃)(CO)ORh(P(C₆H₅)3)2NO₂

There total 2 articles about CH(O)C₆H₂(CH₃)(CO)ORh(P(C₆H₅)3)2NO₂ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

CH(O)C6H2(CH3)(CO)ORh(P(C6H5)3)2Cl (222532-70-9) + sodium nitrite (7632-00-0) → CH(O)C6H2(CH3)(CO)ORh(P(C6H5)3)2NO2 (222532-71-0)

Guidance literature:

In dichloromethane; water; acetone; stirring (0.5 h), evapn.; filtering, washing (H2O), drying (vac.);

DOI:10.1021/om980748e

Reference yield: 94.0%

CH3C6H4NCHC6H2(CH3)(CO)OHRh(P(C6H5)3)2Cl2 + sodium nitrite (7632-00-0) → CH(O)C6H2(CH3)(CO)ORh(P(C6H5)3)2NO2 (222532-71-0) + sodium chloride (7647-14-5)

Guidance literature:

With H₂O; In dichloromethane; acetone; byproducts: CH3C6H4NH2*HCl; stirring (0.5 h), evapn. (reduced pressure); filtering, washing (H2O), drying (vac.); elem. anal.;

DOI:10.1021/om980748e

Reference yield: 95.0%

hydrogenchloride (7647-01-0,15364-23-5) + CH(O)C6H2(CH3)(CO)ORh(P(C6H5)3)2NO2 (222532-71-0) → CH(O)C6H2(CH3)(CO)ORh(P(C6H5)3)2Cl (222532-70-9)

Guidance literature:

In ethanol; water; stirring (0.5 h), evapn.; extg. (H2O), filtering, washing (H2O), drying (vac.);

DOI:10.1021/om980748e

upstream raw materials:

CH(O)C₆H₂(CH₃)(CO)ORh(P(C₆H₅)3)2Cl

sodium nitrite

Downstream raw materials:

CH(O)C₆H₂(CH₃)(CO)ORh(P(C₆H₅)3)2Cl

Refernces