C₁₈H₂₀OS

Base Information

• Chemical Name: C₁₈H₂₀OS
• CAS No.: 129732-85-0
• Molecular Formula: C₁₈H₂₀OS
• Molecular Weight: 284.422
• Mol file: 129732-85-0.mol

Synonyms:C₁₈H₂₀OS

Chemical Property of C₁₈H₂₀OS

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₁₈H₂₀OS

There total 12 articles about C₁₈H₂₀OS which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

(1S,2R)-1-Phenyl-1-phenylsulfanyl-pent-4-en-2-ol + methyl iodide (74-88-4) → C18H20OS (129732-85-0)

Guidance literature:

With potassium hydride; In tetrahydrofuran; at 0 ℃; for 1h;

DOI:10.1021/jo00312a016

Reference yield:

allytriphenyltin (76-63-1) + (1S*,2R*)-1-acetoxy-2-methoxy-1-phenyl-2-(phenylthio)ethane (129732-83-8) → C18H20OS (129732-85-0) + C18H20OS (129732-84-9)

Guidance literature:

With trimethylsilyl trifluoromethanesulfonate; In dichloromethane; at -50 ℃; for 4h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;

DOI:10.1021/jo00312a016

Reference yield:

allytriphenyltin (76-63-1) + (1S*,2S*)-1-acetoxy-2-methoxy-1-phenyl-2-(phenylthio)ethane (129756-71-4) → C18H20OS (129732-85-0) + C18H20OS (129732-84-9)

Guidance literature:

With trimethylsilyl trifluoromethanesulfonate; In dichloromethane; at -50 ℃; for 2h; Yield given. Yields of byproduct given. Title compound not separated from byproducts;

DOI:10.1021/jo00312a016

upstream raw materials:

allyltributylstanane

(1S^*,2R^*)-1-acetoxy-2-methoxy-1-phenyl-2-(phenylthio)ethane

(1S^*,2S^*)-1-acetoxy-2-methoxy-1-phenyl-2-(phenylthio)ethane

allytriphenyltin

Refernces